MATERIAL SAFETY DATA SHEETS

Relating to the various products that Garden Enterprises and Information Ltd, packages and distributes or distributes but does not package.

Updated 17th Novbember 2017

Wallys Borax

Wallys Liquid Copper SDS

Wallys Magic Botanic Liquid (MBL)

Wallys Mycorrcin

Wallys Thatch Busta

Wallys Raingard

Wallys Vaporgard

KMno4 Potassium Permanganate

Caustic Soda

Wallys Ammonium Sulphamate

Wallys Super Compost Accelerator

Wallys Super Stump Rotter

Wallys Karbyon

Wallys Perkfection

Wallys Super Pyrethrum

Wallys Cat Repellent

Wallys Moss & Liverwort Control

Wallys Sulphur Powder

Wallys Super Neem Tree Oil

Wallys Neem Tree Granules/Powder

Wallys Terracin

Wallys Rok Solid

Wallys Secret Strawberry Food

Wallys BioPhos

Wallys Secret Tomato Food

Wallys Secret Tomato Food with Neem Granules

Wallys Secret Cacti and Palm food

Wallys Fruit & Flower Power

Wally Silicon plus Boron Soil Drench

Wallys Silicon Cell Strengthener Spray

Wallys Silicon Super Spreader

Wallys Ocean Solids

Wallys Calcium & Health

Wallys 3 in 1 for Lawns

Wallys Stump Rotter

Dimethyl sulfoxide: [DMSO]

NOTE SDS below are for discontinued products or products which are still in process of selling out (end of lines).

Granny Mins Ant Bait

Baking Soda

Boric Acid (Also Component of Granny Mins Ant Bait)

Copper Sulphate (Soda Ash)

Diatomaceous Earth

Lime Sulphur

Magnesium Sulphate (Epsom Salts)

Matrix

Sodium Carbonate (Soda Ash)

Ammonium Sulphate (Cucumber Booster)

Tergitol NP9


Granny Mins Ant Bait

This product is comprised of 50% Boric acid and 50% Borax see each of the MSD sheets for these chemicals.


Dimethyl sulfoxide: [DMSO]SAFETY DATA SHEET

Revision Date 05/28/2017
1. PRODUCT AND COMPANY IDENTIFICATION
1.1 Product identifiers
Product name : Dimethyl sulfoxide

Product Number : BF1589
Brand : Bofun
CAS-No. : 67-68-5
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Laboratory chemicals, Manufacture of substances
1.3 Details of the supplier of the safety data sheet
Company : SHANG HAIYANCUI IMPORT AND EXPORT CORPORATION
Telephone : 021-38722633
Fax : 021-58500043
1.4 Emergency telephone number
Emergency Phone # : 0086-0-15902216561
2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008. This substance is not classified as dangerous according to Directive 67/548/EEC.
2.2 Label elements The product does not need to be labelled in accordance with EC directives or respective national laws.
2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher
3. COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances
Formula : C2H6OS
Molecular weight : 78.13 g/mol
CAS-No. : 67-68-5
EC-No. : 200-664-3
No components need to be disclosed according to the applicable regulations.
4. FIRST AID MEASURES

4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Flush eyes with water as a precaution. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
4.3 Indication of any imme
No data available
5. FIREFIGHTING MEASURES

5.1 Extinguishing media Suitable extinguishing media For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray; solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water.
5.2 Special hazards arising from the substance or mixture Carbon oxides, Sulphur oxides
5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information Use water spray to cool unopened containers.
6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures Avoid breathing vapours, mist or gas. Remove all sources of ignition. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8.
6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). Keep in suitable, closed containers for disposal.
6.4 Reference to other sections For disposal see section 13
6.5
6.6 0,55 hPa at 20 °C
6.7 2,70 - (Air = 1.0)
6.8 1,1 g/mL completely miscible log Pow: -2,03
6.9 No data available No data available No data available No data available No data available
6.10
6.11 Upper explosion limit: 42 %(V)
6.12 Lower explosion limit: 3,5 %(V)
6.13
6.14 Melting point/range: 16 - 19 °C
6.15 189 °C
6.16 87°C - closed cup No data available No data available
6.17
6.18 Form: liquid, clear Colour: colourless
6.19 No data available No data available No data available
7. HANDLING AND STORAGE

7.1 Precautions for safe handling Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store under inert gas. hygroscopic
7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters Components with workplace control parameters
8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Splash contact Material: Nitrile rubber Minimum layer thickness: 0,2 mm Break through time: 38 min Material tested:DermatrilŽ P (KCL 743 / Aldrich Z677388, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario. Body Protection impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air Sigma - D9170 Page 4 of 7 respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

a) Appearance Form: Liquid Clear Colouless
b) Odour No Data
c) Odour Threshold No Data
d) pH No Data
e) Melting point/freezing point 16-19c
f) Initial boiling point and boiling range 6.15
g) Flash point No Data
h) Evaporation rate No Data
i) Flammability (solid, gas) No Data
j) Upper/lower flammability or explosive limits 42% (v) and 3.5% (v)
k) Vapour pressure No Data
l) Vapour density No Data
m) Relative density No Data
n) Water solubility
o) Partition coefficient: noctanol/ water No Data
p) Auto-ignitiontemperature No Data
q) Decomposition temperature 1,1 g/mL
r) Viscosity completely miscible
s) Explosive properties No
t) Oxidizing properties No Data
9.2 Other safety information Relative vapour density 2,70 - (Air = 1.0)
10. STABILITY AND REACTIVITY

10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
Heat, flames and sparks
10.5 Incompatible materials
Acid chlorides, Phosphorus halides, Strong acids, Strong oxidizing agents, Strong reducing agents
10.6 Hazardous decomposition products
Other decomposition products - No data available
In the event of fire: see section 5
11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects Acute toxicity LD50 Oral - Rat - 14.500 mg/kg LC50 Inhalation - Rat - 4 h - 40250 ppm LD50 Dermal - Rabbit - > 5.000 mg/kg
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
Mouse lymphocyte Cytogenetic analysis Mouse lymphocyte Mutation in mammalian somatic cells. Rat Cytogenetic analysis Mouse DNA damage
Carcinogenicity
Carcinogenicity - Rat - Oral Tumorigenic:Equivocal tumorigenic agent by RTECS criteria. Skin and Appendages: Other: Tumors. Carcinogenicity - Mouse - Oral Tumorigenic:Equivocal tumorigenic agent by RTECS criteria. Leukaemia Skin and Appendages: Other: Tumors. IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC..
Reproductive toxicity
Reproductive toxicity - Rat - Intraperitoneal Effects on Fertility: Abortion. Reproductive toxicity - Rat - Intraperitoneal Effects on Fertility: Post-implantation mortality (e.g., dead and/or resorbed implants per total number of implants). Reproductive toxicity - Rat - Subcutaneous Sigma - D9170 Page 6 of 7 Effects on Fertility: Post-implantation mortality (e.g., dead and/or resorbed implants per total number of implants). Effects on Fertility: Litter size (e.g.; # fetuses per litter; measured before birth). Reproductive toxicity - Mouse - Oral Effects on Fertility: Pre-implantation mortality (e.g., reduction in number of implants per female; total number of implants per corpora lutea). Effects on Embryo or Fetus: Fetotoxicity (except death, e.g., stunted fetus). Specific Developmental Abnormalities: Musculoskeletal system. Developmental Toxicity - Mouse - Intraperitoneal Effects on Embryo or Fetus: Fetotoxicity (except death, e.g., stunted fetus). Specific Developmental Abnormalities: Musculoskeletal system.
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: PV6210000 Effects due to ingestion may include:, Nausea, Fatigue, Headache To the best of our knowledge
12. ECOLOGICAL INFORMATION

12.1 Toxicity Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 34.000 mg/l - 96 h LC50 - Oncorhynchus mykiss (rainbow trout) - 35.000 mg/l - 96 h Toxicity to daphnia and other aquatic invertebrates EC50 - Daphnia magna (Water flea) - 24.600 mg/l - 48 h (OECD Test Guideline 202) Toxicity to algae EC50 - Pseudokirchneriella subcapitata (green algae) - 17.000 mg/l - 72 h (OECD Test Guideline 201)
12.2 Persistence and degradability Biodegradability Result: 31 % - According to the results of tests of biodegradability this product is not readily biodegradable. (OECD Test Guideline 301D)
12.3 Bioaccumulative potential No data available
12.4 Mobility in soil No data available
12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
12.6 Other adverse effects No data available Stability in water - 0,12 - 1,2 h at 30 °C Remarks: Hydrolyses readily.
13.1 Waste treatment methods Product
This combustible material may be burned in a chemical incinerator equipped with an afterburner and scrubber. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material.
Contaminated packaging
Dispose of as unused product.
14. TRANSPORT INFORMATION DOT (US)

Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods
15. REGULATORY INFORMATION

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture No data available
15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out
16. OTHER INFORMATION

Copyright 2015 Tian jin Baofeng Chemical Co. Ltd. License granted to make unlimited paper copies for internal use only. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Baofeng-Aldrich Corporation and its Affiliates shall not be held liable for any damage resulting from handling or from contact with the above product. See www.bf-msm.com and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.



MATERIAL SAFETY DATA SHEET
SODIUM BICARBONATE SDC 685

STATEMENT OF HAZARDOUS NATURE: This material is not classified as a Hazardous material according to the criteria of NZS 5433:1999 "Transport of Dangerous Goods on Land" This material is not a scheduled poison according to the criteria of the Toxic Substances Regulations 1983.
IDENTIFICATION
Product Name: Sodium Bicarbonate
Other Name: Sodium Hydrogen Carbonate, Baking Soda, Bicarbonate of Soda.
Manufacturer's Product Code: Not applicable
U.N. Number: None Allocated
Dangerous Goods Class: None Allocated
Packaging Group: None Allocated
Hazchem Code: None Allocated
Toxic Substances Schedule: Not listed
Physical Description/Properties
Appearance: Fine white powder
Boiling Point/Melting Point: Decomposes 270oC
Vapour Pressure: Not available
Specific Gravity: 2.160
Flash Point: Not available
Flammability Limits: Not available
Solubility in Water: Soluble
Other Properties:
Ingredients Chemical Entity ; CAS No ; Proportion
Sodium Bicarbonate ; 144-55-8 ; 100%.
HEALTH HAZARD INFORMATION
Health Effects
Acute:
Swallowed: Ingestion of large amounts may cause nausea and irritation of stomach.
Eye: Can cause irritation of soft tissue.
Skin: Repeated or prolonged skin contact can lead to mild irritation particularly if skin is moist.
Inhaled: Inhalation of dust may result in respiratory irritation.
Chronic:
First Aid
Swallowed: Do NOT induce vomiting. Rinse mouth with milk or water. Give large amounts of water or milk to drink to achieve dilution. If vomiting occurs give further milk or water. Seek urgent medical assistance.
Eye: Flush affected eye(s) with copious amounts of cold or luke warm water for at least 15 minutes retracting eyelids frequently. Seek medical assistance.
Skin: Flood affected area with copious amounts of soap and water, remove contaminated clothing and launder before reuse. If rash or discolouration appears or persists seek medical assistance.
Inhaled: Remove to fresh air, loosen restrictive clothing. Blow nose thoroughly and swab nasal passages with damp cotton wool. Allow to rest and keep warm. If recovery is not rapid and complete seek medical assistance.
Advice to Doctor: Treat symptomatically. Refer to National Poisons and Hazardous Chemicals Information Centre.
PRECAUTIONS FOR USE
Exposure Standards: Not listed. NZ WES-TWA : Nuisance Dust 10mg/m3
Engineering Controls: Use in well ventilated area. Use protective breathing apparatus as required.
Personal Protection: Wear overalls, rubber gloves and goggles when handling. Wear repirator if local exhaust ventilation inadequate.
Flammability: Non flammable. Decomposes when subjected to extreme heat.
SAFE HANDLING INFORMATION
Storage and Transport: Transport and store in dry cool conditions. Do not store near acids.
Spills and Disposal: Wear protective equipment. Sweep up but avoid generating dust. Prevent contamination of drains and waterways. Collect and seal in containers for disposal in accordance with local authority regulations
Fire/Explosion Hazard: Normally stable. Decomposes to give carbon dioxide and monoxide. Reacts vigorously with acids to liberate carbon dioxide gas.
OTHER INFORMATION

CONTACT POINT
Clark Products Ltd, 24-28 Niven Street Napier
Business Hours 8am to 5pm Monday to Friday
Phone : (06) 843 6049 Fax (06) 843 2758
24 HOUR EMERGENCY HELP
Phone : 0800CHEMCALL (0800 243 622)
National Poisons and Hazardous Chemicals Information Centre
Phone (03) 474 7000
This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all current legislation.

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MATERIAL SAFETY DATA SHEET Boric Acid SDC105

STATEMENT OF HAZARDOUS NATURE: This material is not classified as a Hazardous material according to the criteria of NZS:5433.1999 "Transport of Dangerous Goods on Land". This material is a scheduled poison according to the criteria of the Toxic Substances Regulations 1983.
IDENTIFICATION
Product Name: Boric Acid
Shipping Name: Not Applicable
Manufacturer's Product Code: Not Applicable
U.N. Number: Not Applicable
Dangerous Goods Class: Not Applicable
Packaging Group: Not Applicable
Hazchem Code: Not Applicable
Toxic Substances Schedule: 4
Physical Description/Properties
Appearance: White powder or granules
Boiling Point/Melting Point: MP: 171oC
Vapour Pressure: Not available
Specific Gravity: 1.4 @ 20oC
Flash Point: Not Applicable
Flammability Limits: Not Applicable
Solubility in Water: 4.6% by weight @ 20oC
Other Properties:
Ingredients
Chemical Entity CAS No Proportion
Boric Acid 10043-35-3 99%
Ash to 100%
HEALTH HAZARD INFORMATION
Health Effects

Acute
Swallowed: Abdominal pain, vomiting and diarrhoea
Eye: Irritant
Skin: Mild irritation, harmful if absorbed through broken skin.
Inhaled: Harmful. Irritant to soft tissue.
Chronic Kidney, liver diseases may be aggrevated by exposure to this material.
First Aid
Swallowed: Rinse mouth with milk or water. Induce vomiting by either administering an emetic syrup or putting fingers down throat. Seek urgent medical assistance.
Eye: Flush affected eye(s) with copious amounts of cold or luke warm water for at least 15 minutes retracting eyelids frequently. Seek medical assistance.
Skin: Flood affected area with copious amounts of soap and water, remove contaminated clothing and launder before reuse. If rash or discolouration appears or persists seek medical assistance.
Inhaled: Remove to fresh air, or remove source of contamination. Loosen restrictive clothing. If breathing has stopped apply artificial respiration or CPR immediately. Seek urgent medical assistance
Advice to Doctor: Treat symptomatically. Refer to National Poisons and Hazardous Chemicals Information Centre.
PRECAUTIONS FOR USE
Exposure Standards: NZ WES-TWA: 5mg/m3
Engineering Controls: Avoid generating and inhaling dust. Use with local exhaust ventilation and while wearing respiration. Keep containers closed when not in use.
Personal Protection: Wear overalls, rubber gloves, goggles and dust mask when handling.
Flammability: Non-combustible
SAFE HANDLING INFORMATION
Storage and Transport: Keep dry; avoid excessive heat.
Spills and Disposal: Wear protective equipment. Sweep up but avoid generating dust. Prevent contamination of drains and waterways. Collect and seal in containers for disposal in accordance with local authority regulations
Fire/Explosion Hazard: Non flammable. Stable at ambient temperatures. Does not support combustion. Use firefighting media suitable for surrounding fire.
OTHER INFORMATION

CONTACT POINT
Clark Products Ltd, 24-28 Niven Street Napier
Business Hours 8am to 5pm Monday to Friday
Phone : (06) 843 6049 Fax (06) 843 2758
24 HOUR EMERGENCY HELP
Phone : 0800CHEMCALL (0800 243 622)
National Poisons and Hazardous Chemicals Information Centre
Phone (03) 474 7000
This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all current legislation.

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MATERIAL SAFETY DATA SHEET COPPER SULPHATE SDC205

STATEMENT OF HAZARDOUS NATURE: This material is not classified as a Hazardous material according to the criteria of NZS 5433:1999 "Transport of Dangerous Goods on Land". This material is not a scheduled poison according to the criteria of the Toxic Substances Regulations 1983.
IDENTIFICATION
Product Name: Copper Sulphate
Other Name: Blue Stone, Blue Vitriol, Cupric Sulphate
Manufacturer's Product Code: Not Applicable
U.N. Number: None Allocated
Dangerous Goods Class: None Allocated
Packaging Group: None Allocated
Hazchem Code: None Allocated
Toxic Substances Schedule: Not Listed
Physical Description/Properties
Appearance: Blue crystals or crystalline granules
Boiling Point/Melting Point: Not available
Vapour Pressure: Not available
Specific Gravity: 2.284
Flash Point: Not available
Flammability Limits: Not available
Solubility in Water: Soluble
Other Properties: Ingredients
Chemical Entity CAS No Proportion
Copper sulphate pentahydrate 7758-99-8 >98%
Inerts - to 100%
HEALTH HAZARD INFORMATION
Health Effects
Acute
Swallowed: Acute poisoning shows symptoms of vomiting, gastric pain, dizziness, convulsions, shock, coma and possibly death. As little as 10grams of Copper Sulphate ingestion has been reported as causing death, although victims have recovered after taking far larger doses. Copper salts tend to cause vomiting and for this reason, poisoning by ingestion of large amounts is rare.
Eye: Irritant to mucous tissue.
Skin: Chronic exposure may cause irritation & dermititus
Inhaled: Irritant to mucous tissue.
Chronic Poisoning by ingestion may give rise to kidney damage, enlargement of liver and jaundice.
First Aid
Swallowed: Rinse mouth with milk or water. Induce vomiting by either administering an emetic syrup or putting fingers down throat. Seek urgent medical assistance.
Eye: Flush affected eye(s) with copious amounts of cold or luke warm water for at least 15 minutes retracting eyelids frequently. Seek medical assistance.
Skin: Flood affected area with copious amounts of soap and water, remove contaminated clothing and launder before reuse. If rash or discolouration appears or persists seek medical assistance.
Inhaled: Remove to fresh air, loosen restrictive clothing. Blow nose thoroughly and swab nasal passages with damp cotton wool. Allow to rest and keep warm. If recovery is not rapid and complete seek medical assistance.
Advice to Doctor: Treat symptomatically. Refer to National Poisons and Hazardous Chemicals Information Centre.
PRECAUTIONS FOR USE
Exposure Standards: NZ WES-TWA Copper dusts 1mg/m3 (as copper)
Engineering Controls: Natural ventilation should be adequate under normal use conditions. Avoid generating and inhaling dust.
Personal Protection: Wear overalls, rubber gloves, goggles and dust mask when handling.
Flammability: The material is non-flammable.
SAFE HANDLING INFORMATION
Storage and Transport: Store in cool dry place.
Spills and Disposal: Wear protective equipment. Sweep up but avoid generating dust. Prevent contamination of drains and waterways. Collect and seal in containers for disposal in accordance with local authority regulations
Fire/Explosion Hazard: Non flammable. Stable at ambient temperatures. Does not support combustion. Use firefighting media suitable for surrounding fire.
OTHER INFORMATION
CONTACT POINT

Clark Products Ltd, 24-28 Niven Street Napier
Business Hours 8am to 5pm Monday to Friday
Phone : (06) 843 6049 Fax (06) 843 2758
24 HOUR EMERGENCY HELP
Phone : 0800CHEMCALL (0800 243 622)
National Poisons and Hazardous Chemicals Information Centre
Phone (03) 474 7000
This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all current legislation.
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MATERIAL SAFETY DATA SHEET DIATOMACEOUS EARTH SDC245

STATEMENT OF HAZARDOUS NATURE: This material is not classified as a Hazardous material according to the criteria of NZS 5433:1999 "Transport of Dangerous Goods on Land". This material is not a scheduled poison according to the criteria of the Toxic Substances Regulations 1983.
IDENTIFICATION
Product Name: Diatomaceous Earth
Other Name: Filter powder, Diatomite, Dicalite, Celatom
Manufacturer's Product Code: Not Applicable
U.N. Number: None Allocated
Dangerous Goods Class: None Allocated
Packaging Group: None Allocated
Hazchem Code: None Allocated
Toxic Substances Schedule: Not Listed
Physical Description/Properties
Appearance: White to off-white powder, odourless
Boiling Point/Melting Point: Sintering point : 1593oC
Vapour Pressure: Not available
Specific Gravity: 2.3
Flash Point: Not applicable
Flammability Limits: Not applicable
Solubility in Water: Slight
Other Properties:
Ingredients
Chemical Entity CAS No Proportion
Fluxcalcined Diatomaceous Earth 68855-54-9 100%
HEALTH HAZARD INFORMATION
Health Effects
Acute
Swallowed: Low Toxicity
Eye: Dust may cause severe irritation.
Skin: Non-irritant
Inhaled: Dust may cause irritation, may aggravate asthma, bronchitis, emphysema.
Chronic Long term exposure to silica dusts may cause pnenmonconiosis and silicosis.
First Aid
Swallowed: Seek medical advice
Eye: Flush affected eye(s) with copious amounts of cold or luke warm water for at least 15 minutes retracting eyelids frequently. Seek medical assistance.
Skin: Flood affected area with copious amounts of soap and water, remove contaminated clothing and launder before reuse. If rash or discolouration appears or persists seek medical assistance.
Inhaled: Remove to fresh air, loosen restrictive clothing and allow to rest. Keep warm. If recovery is not rapid and complete seek medical assistance.
Advice to Doctor: Persons with impaired lung function or asthma, may suffer increased difficulty breathing, after inhalation of this dust.
PRECAUTIONS FOR USE
Exposure Standards: NZ WES TWA:Amorphous silica 10mg/m3
Engineering Controls: Use in well ventilated area. Use protective breathing apparatus as required.
Personal Protection: Wear overalls, rubber gloves, goggles and dust mask when handling.
Flammability: Non flammable
SAFE HANDLING INFORMATION
Storage and Transport: Store in cool, dry place, avoid damaging bags while in transit or storage. Incompatible with Hyphafluoric acid.
Spills and Disposal: Wear protective equipment. Sweep up but avoid generating dust. Prevent contamination of drains and waterways. Collect and seal in containers for disposal in accordance with local authority regulations.
Fire/Explosion Hazard: Will not burn. Containers exposed to fire may be cooled with water.
OTHER INFORMATION
CONTACT POINT

Clark Products Ltd, 24-28 Niven Street Napier
Business Hours 8am to 5pm Monday to Friday
Phone : (06) 843 6049 Fax (06) 843 2758
24 HOUR EMERGENCY HELP
Phone : 0800CHEMCALL (0800 243 622)
National Poisons and Hazardous Chemicals Information Centre
Phone (03) 474 7000
This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all current legislation.

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PRODUCT
Trade Name Wallys LIME SULPHUR
Product Dormant season fungicide, insecticide, miticide
Formulation type Soluble Concentrate
Ingredients 1. Calcium Polysulphide
2. Water
Active ingredient(s) Sulphur as Polysulphide of calcium
Fungicidal and Dessicant action via alkalinity. oxidises to elemental sulphur
PHYSICAL
Specific Gravity 1000g per litre
Solubility in Water Readily Soluble
Flammability Non-Flammable.
HAZARD IDENTIFICATION
Inhalation AVOID INHALING FUMES, OR SPRAY MIST. SULPHIDE FUMES MAY RESULT IN RESPIRATORY UPSET.
Eye irritation AVOID CONTACT WITH EYES. PRODUCT IS CORROSIVE AND ALKALINE,
Skin Absorption AVOID CONTACT WITH SKIN. PRODUCT IS IRRITANT
Ingestion CAN CAUSE SERIOUS INTERNAL DAMAGE IF SWALLOWED
Chronic NONE
Re-entry When Dry
TOXICOLOGY
MODERATE TOXICITY
ORAL LD50 -
DERMAL LD50 -
INHALATION -
ECOTOXICITY -.
FIRST AID MEASURES
Inhalation Remove patient to fresh air. If respiratory symptoms arise consult physician.
Eye Contact Wash eyes with plenty of warm water for approximately 15 minutes. Seek medical assistance.
Skin Contact Remove clothing from affected area, and wash with warmwater and detergent. If allergic reaction arises consult physician.
Ingestion Give plenty of water.
Emergency Treatment No recommended procedures.
ACCIDENTAL SPILLAGE
Land Spill Absorb and dispose of spilt material, then flush area with water. Ventilate area.
Contamination of waterway Avoid further spillage of concentrate into waterway. Ensure adequate dilution of spilt material.
HANDLING AND STORAGE
Storage Store Sealed , dry under cool dark conditions
Exposure and Personal Protection
Applicators Protective clothing - EYE SKIN RESPIRATOR required for application.
Re-Packaging of Product Skin Protection (gloves), Respiratory and eye protection required.
Re pack product in a well ventilated area.

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MATERIAL SAFETY DATA SHEET
MAGNESIUM SULPHATE SDC420

STATEMENT OF HAZARDOUS NATURE: This material is not classified as a Hazardous material according to the criteria of NZS 5433:1999 "Transport of Dangerous Goods on Land" This material is not a scheduled poison according to the criteria of the Toxic Substances Regulations 1983.
IDENTIFICATION
Product Name: Magnesium Sulphate
Other Name: Epsom Salts
Manufacturer's Product Code: Not Applicable
U.N. Number: None Allocated
Dangerous Goods Class: None Allocated
Packaging Group: None Allocated
Hazchem Code: None Allocated
Toxic Substances Schedule: Not Listed
Physical Description/Properties
Appearance: White, fine, odouless colorless crystals
Boiling Point/Melting Point: Decomposes @ 1124oC
Vapour Pressure: Not Available
Specific Gravity: Not Available
Flash Point: Not Available
Flammability Limits: Not Available
Solubility in Water: Very Soluble
Other Properties: Soluble in Glycerol
Ingredients
Chemical Entity CAS No Proportion
Magnesium Sulfate 7587-88-9 100%
HEALTH HAZARD INFORMATION
Health Effects
Acute
Swallowed: Ingestion of large amounts may cause thirst, flushing of skin, and respiratory dysfunction.
Eye: Can cause irritation to mucous and tissue.
Skin: Can cause irritation of sensitive skin.
Inhaled: Inhalation of solid material can cause nasal and respiratory tract irritation.
Chronic No data available
First Aid
Swallowed: Do NOT induce vomiting. Rinse mouth with milk or water. Give large amounts of water or milk to drink to achieve dilution. If vomiting occurs give further milk or water. Seek urgent medical assistance.
Eye: Flush affected eye(s) with copious amounts of cold or luke warm water for at least 15 minutes retracting eyelids frequently. Seek medical assistance.
Skin: Flood affected area with copious amounts of soap and water, remove contaminated clothing and launder before reuse. If rash or discolouration appears or persists seek medical assistance.
Inhaled: Remove to fresh air, loosen restrictive clothing. Blow nose thoroughly and swab nasal passages with damp cotton wool. Allow to rest and keep warm. If recovery is not rapid and complete seek medical assistance
Advice to Doctor: Magnesium Salts are generally of low toxicity and are normally rapidly excreted from the body. Systemic poisoning can occur where there is a history of impaired renal function. Treat as appropriate to symptoms evident.
PRECAUTIONS FOR USE
Exposure Standards: Not listed. NZ WES-TWA: Nuisance Dust 10 mg/m3
Engineering Controls: Natural ventilation should be adequate under normal use conditions. Avoid generating and inhaling dust.
Personal Protection: Wear overalls, rubber gloves, goggles and dust mask when handling.
Flammability: Non-Flammable - will not support combustion.
SAFE HANDLING INFORMATION
Storage and Transport: Keep dry and cool
Spills and Disposal: Wear protective equipment. Sweep up but avoid generating dust. Prevent contamination of drains and waterways. Collect and seal in containers for disposal in accordance with local authority regulations.
Fire/Explosion Hazard: Non flammable. Stable at ambient temperatures. Does not support combustion. Use fire fighting media suitable for surrounding fire.
OTHER INFORMATION
CONTACT POINT
Clark Products Ltd, 24-28 Niven Street Napier
Business Hours 8am to 5pm Monday to Friday
Phone : (06) 843 6049 Fax (06) 843 2758
24 HOUR EMERGENCY HELP
Phone : 0800CHEMCALL (0800 243 622)

National Poisons and Hazardous Chemicals Information Centre
Phone (03) 474 7000
This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all current legislation.

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PRODUCT

Trade Name Matrix Reloaded
Product HORTICULTURAL FERTILIZER
Manufacturer Otaki Hydroponics ltd.
Formulation type Suspension Concentrate
Ingredients: Calcium Nitrate, MonoPotassium Phosphate, Potassium Nitrate, magnesium Sulphate, Iron EDTA, Manganese Sulfate, Boric Acid, Zinc Sulfate, Copper Sulfate, Ammonium Molybdate, Nickel Sulfate, Cobalt Sulfate, Potassium Iodide, Potassium Dichromate, Sodium Selenate, Acozine blue or Rubinol red, Synthetic stabilising agent (gum).
Active ingredient(s) Mineral ions
PHYSICAL
Specific Gravity 1000 g per litre
Solubility in Water Soluble.
Flammability Non-Flammable. Non Explosive.
HAZARD IDENTIFICATION
Inhalation NONE
Eye irritation MILDLY ACIDIC, HIGHLY SALINE as CONCENTRATE.
Skin Absorption NONE- ALTHOUGH CAN HAVE IRRITANT EFFECT ON EXPOSED SKIN
Ingestion NONE
CHRONIC Long Term exposure to nitrates and some trace elements can be damaging to health.
TOXICOLOGY
ORAL LD50 - (NON TOXIC)
DERMAL LD50 -
Ecotoxicity May cause algal bloom. Can be toxic to fish.
FIRST AID MEASURES
Inhalation NONE REQUIRED.
Eye Contact Wash eyes with plenty of warm water for approximately 15 minutes. Seek medical assistance if allergic reaction occurs.
Skin Contact Remove clothing from affected area, and wash with warmwater and detergent. If allergic reaction arises consult physician.
Ingestion No recommended procedures.
Emergency Treatment No recommended procedures.
ACCIDENTAL SPILLAGE
Land Spill Absorb and dispose of spilt material. Flush area with hot water to reduce residue.
Contamination of waterway Avoid further spillage of concentrate into waterway. Ensure adequate dilution of spilt material.
HANDLING AND STORAGE
Storage Store dry under cool dark conditions
EXPOSURE AND PERSONAL PROTECTION
Applicators Minimal Protective clothing required for application.
Re-Packaging of Product Skin Protection (gloves) recommended.

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MATERIAL SAFETY DATA SHEET
SDC485 - Nansa HS 80AU

STATEMENT OF HAZARDOUS NATURE: This material is not classified as a Hazardous material according to the criteria of NZS 5433:1999 "Transport of Dangerous Goods on Land" This material is not a scheduled poison according to the criteria of the Toxic Substances Regulations 1983.
IDENTIFICATION
Product Name: Nansa HS 80AU
Other Name: Sodium Alkylbenzene Sulphonate, sodium dodecylbenzene sulphonate
Manufacturer's Product Code: Not Applicable
U.N. Number: None Allocated
Dangerous Goods Class: None Allocated
Packaging Group: None Allocated
Hazchem Code: None Allocated
Toxic Substances Schedule: Not listed
Physical Description/Properties
Appearance: White to cream coloured free flowing powder.
Boiling Point/Melting Point: Not available
Vapour Pressure: Not available
Specific Gravity: Packing Density: 0.55
Flash Point: Not available
Flammability Limits: Not available
Solubility in Water: approx 150g/l (20 degrees celcius)
Other Properties:
Ingredients
Chemical Entity CAS No Proportion
Sodium Alkylbenzene sulphate 68081-81-2 80%
Sodium Sulphate 7757-82-6 14%
Non Hazardous inerts ----------- to 100%
HEALTH HAZARD INFORMATION
Health Effects
Acute
Swallowed: Moderate irritant
Eye: Dust is eye irritant
Skin: Prolonged or repeated contact may produce dermatitis
Inhaled: Dust is irritating to nose, throat and lungs.
Chronic No data available
First Aid
Swallowed: Do NOT induce vomiting. Rinse mouth with milk or water. Give large amounts of water or milk to drink to achieve dilution. If vomiting occurs give further milk or water. Seek urgent medical assistance.
Eye: Flush affected eye(s) with copious amounts of cold or luke warm water for at least 15 minutes retracting eyelids frequently. Seek medical assistance.
Skin: Flood affected area with copious amounts of soap and water, remove contaminated clothing and launder before reuse. If rash or discolouration appears or persists seek medical assistance.
Inhaled: Remove to fresh air, loosen restrictive clothing. Blow nose thoroughly and swab nasal passages with damp cotton wool. Allow to rest and keep warm. If recovery is not rapid and complete seek medical assistance
Advice to Doctor: Treat symptomatically. Refer to National poisons and Hazardous Chemicals Information Centre.
PRECAUTIONS FOR USE
Exposure Standards: Not listed. NZ WES-TWA: Nuisance Dust 10 mg/m3
Engineering Controls: Use in well ventilated area. Use protective breathing apparatus as required.
Personal Protection: Wear overalls, rubber gloves and goggles when handling. Wear repirator if local exhaust ventilation inadequate.
Flammability: Not flammable. Does not support combustion.
SAFE HANDLING INFORMATION
Storage and Transport: Store in a dry place away from foodstuffs and oxidising agents. Bags should be protected from damage and mild stell drums should not be used for prolonged storage of solutions of these products. Keep containers tightly closed when not in use to prevent moisture absorbtion and craking.
Spills and Disposal: Wear protective equipment. Sweep up but avoid generating dust. Prevent contamination of drains and waterways. Collect and seal in containers for disposal in accordance with local authority regulations.
Fire/Explosion Hazard: Not flammable but in a large fire may evolve toxic fumes containing sulphur dioxide and carbon monoxide.
OTHER INFORMATION
CONTACT POINT
Clark Products Ltd, 24-28 Niven Street Napier
Business Hours 8am to 5pm Monday to Friday
Phone : (06) 843 6049 Fax (06) 843 2758
24 HOUR EMERGENCY HELP
Phone : 0800CHEMCALL (0800 243 622)
National Poisons and Hazardous Chemicals Information Centre
Phone (03) 474 7000
This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all current legislation.
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MATERIAL SAFETY DATA SHEET
SODIUM CARBONATE SDC705
STATEMENT OF HAZARDOUS NATURE: This material is not classified as a Hazardous material according to the criteria of NZS 5433:1999 "Transport of Dangerous Goods on Land" This material is not a scheduled poison according to the criteria of the Toxic Substances Regulations 1983.
IDENTIFICATION
Product Name: Sodium Carbonate
Other Name: Soda Ash, Carbonic Acid (Disodium Salt), Dry Alkali.
Manufacturer's Product Code: Not Applicable.
U.N. Number: None Allocated
Dangerous Goods Class: None Allocated
Packaging Group: None Allocated
Hazchem Code: None Allocated
Toxic Substances Schedule: Not Listed
Physical Description/Properties
Appearance: White crystalline or granular solid.
Boiling Point/Melting Point: MP: 851oC
Vapour Pressure: Not available
Specific Gravity: 2.530
Flash Point: Not available
Flammability Limits: Not available
Solubility in Water: Soluble
Other Properties: Insoluble in alcohol
Ingredients
Chemical Entity CAS No Proportion
Sodium Carbonate 497-19-8 100%
HEALTH HAZARD INFORMATION
Health Effects
Acute
Swallowed: Ingestion of large amounts could cause nausea, vomiting and diarrhoea.
Eye: Strong irritant to soft tissue and eyes.
Skin: Irritant to skin, particularly if skin is wet or moist due to sweating. Solutions are severely irritant due to alkaline nature.
Inhaled: Will result in respiratory and nasal irritation.
Chronic No data available.
First Aid
Swallowed: Do NOT induce vomiting. Rinse mouth with milk or water. Give large amounts of water or milk to drink to achieve dilution. If vomiting occurs give further milk or water. Seek urgent medical assistance.
Eye: Flush affected eye(s) with copious amounts of cold or luke warm water for at least 15 minutes retracting eyelids frequently. Seek medical assistance.
Skin: Flood affected area with copious amounts of soap and water, remove contaminated clothing and launder before reuse. If rash or discolouration appears or persists seek medical assistance.
Inhaled: Remove to fresh air, loosen restrictive clothing. Blow nose thoroughly and swab nasal passages with damp cotton wool. Allow to rest and keep warm. If recovery is not rapid and complete seek medical assistance.
Advice to Doctor: Treat symptomatically. Refer to National Poisons and Hazardous Chemicals Information Centre.
PRECAUTIONS FOR USE
Exposure Standards: Not listed. NZ WES-TWA : Nuisance Dust 10mg/m3
Engineering Controls: Use in well ventilated area. Use protective breathing apparatus as required.
Personal Protection: Wear overalls, rubber gloves and goggles when handling. Wear repirator if local exhaust ventilation inadequate.
Flammability: Non Flammable.
SAFE HANDLING INFORMATION
Storage and Transport: Keep dry and away from acids.
Spills and Disposal: Wear protective equipment. Sweep up but avoid generating dust. Prevent contamination of drains and waterways. Collect and seal in containers for disposal in accordance with local authority regulations
Fire/Explosion Hazard: No hazard in normal use and storage. Will react violently with acids releasing heat and carbon dioxide.
OTHER INFORMATION
CONTACT POINT
Clark Products Ltd, 24-28 Niven Street Napier
Business Hours 8am to 5pm Monday to Friday
Phone : (06) 843 6049 Fax (06) 843 2758
24 HOUR EMERGENCY HELP
Phone : 0800CHEMCALL (0800 243 622)
National Poisons and Hazardous Chemicals Information Centre
Phone (03) 474 7000
This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all current legislation.

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MATERIAL SAFETY DATA SHEET
AMMONIUM SULPHATE SDC065

STATEMENT OF HAZARDOUS NATURE: This material is not classified as a Hazardous material according to the criteria of NZS 5433:1999 "Transport of Dangerous Goods on Land". This material is not a scheduled poison according to the criteria of the Toxic Substances Regulations 1983.
IDENTIFICATION
Product Name: Ammonium Sulphate
Other Name: Not Applicable
Manufacturer's Product Code: Not Applicable
U.N. Number: None Allocated
Dangerous Goods Class: None Allocated
Packaging Group: None Allocated
Hazchem Code: None Allocated
Toxic Substances Schedule: Not Listed
Physical Description/Properties
Appearance: Brownish grey to white crystals
Boiling Point/Melting Point: Decomposes above 235oC
Vapour Pressure: Not available
Specific Gravity: 1.77
Flash Point: Not Available
Flammability Limits: Not Available
Solubility in Water: 76g/100ml
Other Properties:
Ingredients
Chemical Entity CAS No Proportion
Ammonium Sulphate 7783-20-2 99.5%
Inerts - to 100%
HEALTH HAZARD INFORMATION
Health Effects
Acute
Swallowed: Low to medium toxicity may cause sore throat, abdominal pain, nausea and vomiting.
Eye: Dust will cause moderate irritation redness and watering.
Skin: Moderate irritant may cause redness or itching.
Inhaled: Moderate irritant may cause sore throat and/or coughing.
Chronic No data available
First Aid
Swallowed: Rinse mouth with milk or water. Induce vomiting by either administering an emetic syrup or putting fingers down throat. Seek urgent medical assistance.
Eye: Flush affected eye(s) with copious amounts of cold or luke warm water for at least 15 minutes retracting eyelids frequently. Seek medical assistance.
Skin: Flood affected area with copious amounts of soap and water, remove contaminated clothing and launder before reuse. If rash or discolouration appears or persists seek medical assistance.
Inhaled: Remove victim to fresh air loosen restrictive clothing and allow to rest. Keep warm. If recovery is not rapid and complete seek medical assistance.
Advice to Doctor: Treat symptomatically. Refer to National Poisons and Hazardous Chemicals Information Centre.
PRECAUTIONS FOR USE
Exposure Standards: Not listed. NZ WES-TWA : Nuisance Dust 10mg/m3
Engineering Controls: Use in well ventilated area. Use protective breathing apparatus as required.
Personal Protection: Wear overalls, rubber gloves and goggles when handling. Wear repirator if local exhaust ventilation inadequate.
Flammability: Non Flammable.
SAFE HANDLING INFORMATION
Storage and Transport: Keep cool and dry. Store away from bases and heat. Corrosive to metals.
Spills and Disposal: Wear protective equipment. Sweep up but avoid generating dust. Prevent contamination of drains and waterways. Collect and seal in containers for disposal in accordance with local authority regulations
Fire/Explosion Hazard: Non flammable. Stable at ambient temperatures. Does not support combustion. Use firefighting media suitable for surrounding fire. Decomposes to release toxic sulphur dioxide fumes.
OTHER INFORMATION
CONTACT POINT
Clark Products Ltd, 24-28 Niven Street Napier
Business Hours 8am to 5pm Monday to Friday
Phone : (06) 843 6049 Fax (06) 843 2758
24 HOUR EMERGENCY HELP
Phone : 0800CHEMCALL (0800 243 622)
National Poisons and Hazardous Chemicals Information Centre
Phone (03) 474 7000
This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all current legislation.

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MATERIAL SAFETY DATA SHEET
Tergitol NP9

Was used as an emulsifier in Wallys Neem Tree Oil. STATEMENT OF HAZARDOUS NATURE: This material is classified as a Hazardous material according to the criteria of NZS 5433:1999 "Transport of Dangerous Goods on Land" This material is not a scheduled poison according to the criteria of the Toxic Substances Regulations 1983.
IDENTIFICATION
Product Name: Tergitol NP9
Other Name: Nonylphenol Ethoxylate
Manufacturer's Product Code: Not Applicable
U.N. Number: 3082
Dangerous Goods Class: 9 (Environmentally Hazardous Substance)
Packaging Group: III
Hazchem Code: 2X
Toxic Substances Schedule: Not Listed
Physical Description/Properties
Appearance: Clear to hazy viscous liquid.
Boiling Point/Melting Point: BP:> 250oC, MP 3.8oC
Vapour Pressure: <0.01mm Hg (20oC)
Specific Gravity: 1.057 (20/20oC)
Flash Point: 247oC (Pensky-Martens c.c.)
Flammability Limits: Not available
Solubility in Water: Soluble
Other Properties: Soluble in most organic solvents
Ingredients
Chemical Entity CAS No Proportion
Nonyl phenol
Ethoxylated with 9 moles of ethylene oxide 9016-45-9 100%
HEALTH HAZARD INFORMATION
Health Effects
Acute
Swallowed: May cause abdominal discomfort, nausea, vomiting and diarrhoea. Aspiration into lungs may cause injury.
Eye: Causes severe irritation with possible chemical burns of the eye.
Skin: Will have a degreasing effect on the skin. Brief contact is not irritating. Prolonged contact my cause redness.
Inhaled: Not normally an inhalation hazard due to low vapour pressure at ambient temperature.
Chronic Repeated or prolonged contact may lead to dermatitus
First Aid
Swallowed: Do NOT induce vomiting. Rinse mouth with milk or water. Give large amounts of water or milk to drink to achieve dilution. If vomiting occurs give further milk or water. Seek urgent medical assistance.
Eye: Flush affected eye(s) with copious amounts of cold or luke warm water for at least 15 minutes retracting eyelids frequently. Seek medical assistance.
Skin: Flood affected area with copious amounts of soap and water, remove contaminated clothing and launder before reuse. If rash or discolouration appears or persists seek medical assistance.
Inhaled: Remove victim to fresh air loosen restrictive clothing and allow to rest. Keep warm. If recovery is not rapid and complete seek medical assistance.
Advice to Doctor: Treat symptomatically. Refer to National Poisons and Hazardous Chemicals Information Centre.
PRECAUTIONS FOR USE
Exposure Standards: Not listed.
Engineering Controls: Natural ventilation should be adequate under normal use conditions. Avoid generating and inhaling dust.
Personal Protection: Wear overalls, rubber gloves and goggles when handling.
Flammability: Combustible liquid.
SAFE HANDLING INFORMATION
Storage and Transport: Normally unreactive. Do not store with oxidising agents. Keep containers closed when not in use.
Spills and Disposal: Slippery when spilt. Avoid accidents and clean up immediately. Small spills of liquid should be absorbed with suitable inert dry matter such as sand or diatomaceous earth. For large spills, prevent liquid from spreading by use of sand, etc. Transfer recovered liquid to salvage tank or drum. Treat residues as for small spillage. Dispose of any contaminated material in accordance with local authority regulations.
Fire/Explosion Hazard: Burning can produce carbon monoxide or carbon dioxide.
OTHER INFORMATION
CONTACT POINT
Clark Products Ltd, 24-28 Niven Street Napier
Business Hours 8am to 5pm Monday to Friday
Phone : (06) 843 6049 Fax (06) 843 2758
24 HOUR EMERGENCY HELP
Phone : 0800CHEMCALL (0800 243 622)
National Poisons and Hazardous Chemicals Information Centre
Phone (03) 474 7000
This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all current legislation.

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