MATERIAL SAFETY DATA SHEETS

Relating to the various products that Garden Enterprises and Information Ltd, packages and distributes or distributes but does not package.

Updated 18th September 2017

Wallys Borax

Wallys Liquid Copper SDS

Wallys Magic Botanic Liquid (MBL)

Wallys Mycorrcin

Wallys Thatch Busta

Wallys Raingard

Wallys Vaporgard

KMno4 Potassium Permanganate

Caustic Soda

Wallys Ammonium Sulphamate

Wallys Super Compost Accelerator

Wallys Super Stump Rotter

Wallys Karbyon

Wallys Perkfection

Wallys Super Pyrethrum

Wallys Cat Repellent

Wallys Moss & Liverwort Control

Wallys Sulphur Powder

Granny Mins Ant Bait

BIOPHOS

Rok Solid

Wallys Fruit and Flower Power

Wallys 3 in 1 for lawns

Baking Soda

Boric Acid (Also Component of Granny Mins Ant Bait)

Wallys Calcium & Health

Copper Sulphate (Soda Ash)

Diatomaceous Earth

Dimethyl sulfoxide: [DMSO]

Lime Sulphur

Magnesium Sulphate (Epsom Salts)

Matrix

Wallys Neem Tree Oil TM

Wallys Super Neem Tree Oil

Wallys Neem Tree Granules TM & Wallys Neem Tree Powder TM

Potassium Nitrate (Stump Rotter & Cucumber Booster)

Sodium Carbonate (Soda Ash)

Ammonium Sulphate (Cucumber Booster)

Tergitol NP9

Wallys Silicon plus Boron Soil Drench

Wallys Cell Strenthener Spray

Wallys Silicon Super Spreader


Granny Mins Ant Bait

This product is comprised of 50% Boric acid and 50% Borax see each of the MSD sheets for these chemicals.


MATERIAL SAFETY DATA SHEET

SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME : TERRA NEEM OIL; sold in NZ as WALLYS SUPER NEEM TREE OIL

PRODUCT DESCRIPTION: NEEM OIL

M/s Sun BioNaturals ( India) Pvt.Ltd.
Sun Tower, Super A 7, TVK Industrial Estate,Guindy
Chennai,Tamilnadu, India- 600 032
[ Emergency contact number : +91-44-32001102/43552518 ]
Wallys Super Neem Tree Oil emulsified
Garden Enterprises & Information Ltd
147 Benmore Ave
Palmerston North
0800466464
Emergency Telephone: CHEMCALL 0800 243 622 (ALL HOURS)
SECTION 2 COMPOSITION , INFORMATION ON INGREDIENTS

Description : Neem seed kernel extracted oil
Composition : 99.96 % Neem Seed Kernel Oil .04% emulsifier
Ingredient : Neem Seed
CAS NO : 8002-65-1
EICNES NO : 273-313-5
SECTION 3 - HAZARDS IDENTIFICATION

Emergency Overview
This product is a brown color liquid of neem seed kernel used As fertilizer or pesticide raw material and medicinal and human health filed.
This product Pose no health concerns through normal use in accordance with label Directions
Potential health effects
Routes of entry Eyes, skin, oral, inhalation
Human effects and- Symptoms of overexposure None noted
Acute eye contact May cause Mild reversible eye irritation
Chronic eye contact Chronic exposure not likely from normal use
Acute Skin contact None noted
Chronic skin contract None noted
Acute inhalation None noted
Chronic inhalation None noted
SECTION 4 FIRST AID MEASURES

Fist aid for eyes Flush immediately with plenty of water, seek Medical attention if irritation persists
First aid for skin Wash with soap and water , seek medical Attention if irritation develops or persists
First aid for inhalation Remove to fresh air , seek medical attention If irritation persists
First aid for ingestion Do not induce vomiting , Drink 2-3 Glasses of Water , contact physician for further treatment
SECTION 5 - FIRE AND EXPLOSION DATA

None noted
Extinguishing media Natural oil , Carbon dioxide or Halon extinguisher
Unusual fire and explosion hazards None
Special fire fighting procedures None
SECTION 6 ACCIDENTAL RELEASE MEASURES

Spills Sweep up and place in an appropriate container , Hold for disposal . Wash spilled surfaces to remove any residue
SECTION 7 HANDELING AND STORE

Handling Wash thoroughly after handling
Storage Store in a cool dry place , keep tightly Closed
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Personal Protective equipment
Eyes Water safety Glasses
Skin Protective cloth is not necessary
Respiratory / Ventilation requirement Use with adequate ventilation
Exposure limits None
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Appearance Natural Brown color oil
Melting point 55*F / 13*C
Boiling point 310*F / 154*C
Specific gravity 0.924 at 27*C
Vapor pressure Not applicable
Vapor Density Not applicable
Solubility in water Not soluble
Odor Characteristic odor
Evaporation rate Not applicable
Molecular weight Not applicable
SECTION 10 - STABILITY AND REACTIVITY

Stability Stable
Reactivity None noted
SECTION 11 TOXICOLOGY INFORMATION

Ingestion No toxic Oral LD50 (Rat) > 5000mg/kg body weight
Dermal No toxic Dermal LD50 (Rat) > 5000mg/kg body weight
Inhalation No toxic LC50 (Rat): 1.1ml/litre of air
Eye Contact Non irritable (Rabbit)
Skin Contact Not Available
Skin Sensitization Not Available
Other Toxicity Not Available
SECTION 12 ECOLOGICAL INFORMATION

Ecotoxicity N/A
Environmental fate N/A
SECTION 13 DISPOSAL CONSIDERATION

Disposal : Disposal should be handled through a licensed Waste disposal service
SECTION 14 TRANSPORTATION INFORMATION

Non-Hazardous & Non- Dangerous Material. It can be carried in a passenger aircraft. It is safe to travel IATA.
SECTION 15 - REGULATORY INFORMATION

OSHA Status N/A
TSCA Status N/A
RCRA Status N/A
SECTION 16 OTHER INFORMATION

THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT ON THE DATE IT IS PUBLISHED AND MUST NOT BE CONSIDERED ALL INCLUSIVE FINAL DETERMINATION OF SUITABLITY OF ANY MATERIAL IS THE SOLE RESPONSIBILITY OF THE USER
Reviewed 11th September 2017


Dimethyl sulfoxide: [DMSO]SAFETY DATA SHEET

Revision Date 05/28/2017
1. PRODUCT AND COMPANY IDENTIFICATION
1.1 Product identifiers
Product name : Dimethyl sulfoxide

Product Number : BF1589
Brand : Bofun
CAS-No. : 67-68-5
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Laboratory chemicals, Manufacture of substances
1.3 Details of the supplier of the safety data sheet
Company : SHANG HAIYANCUI IMPORT AND EXPORT CORPORATION
Telephone : 021-38722633
Fax : 021-58500043
1.4 Emergency telephone number
Emergency Phone # : 0086-0-15902216561
2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008. This substance is not classified as dangerous according to Directive 67/548/EEC.
2.2 Label elements The product does not need to be labelled in accordance with EC directives or respective national laws.
2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher
3. COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances
Formula : C2H6OS
Molecular weight : 78.13 g/mol
CAS-No. : 67-68-5
EC-No. : 200-664-3
No components need to be disclosed according to the applicable regulations.
4. FIRST AID MEASURES

4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Flush eyes with water as a precaution. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
4.3 Indication of any imme
No data available
5. FIREFIGHTING MEASURES

5.1 Extinguishing media Suitable extinguishing media For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray; solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water.
5.2 Special hazards arising from the substance or mixture Carbon oxides, Sulphur oxides
5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information Use water spray to cool unopened containers.
6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures Avoid breathing vapours, mist or gas. Remove all sources of ignition. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8.
6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). Keep in suitable, closed containers for disposal.
6.4 Reference to other sections For disposal see section 13
6.5
6.6 0,55 hPa at 20 C
6.7 2,70 - (Air = 1.0)
6.8 1,1 g/mL completely miscible log Pow: -2,03
6.9 No data available No data available No data available No data available No data available
6.10
6.11 Upper explosion limit: 42 %(V)
6.12 Lower explosion limit: 3,5 %(V)
6.13
6.14 Melting point/range: 16 - 19 C
6.15 189 C
6.16 87C - closed cup No data available No data available
6.17
6.18 Form: liquid, clear Colour: colourless
6.19 No data available No data available No data available
7. HANDLING AND STORAGE

7.1 Precautions for safe handling Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store under inert gas. hygroscopic
7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters Components with workplace control parameters
8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Splash contact Material: Nitrile rubber Minimum layer thickness: 0,2 mm Break through time: 38 min Material tested:Dermatril P (KCL 743 / Aldrich Z677388, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario. Body Protection impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air Sigma - D9170 Page 4 of 7 respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

a) Appearance Form: Liquid Clear Colouless
b) Odour No Data
c) Odour Threshold No Data
d) pH No Data
e) Melting point/freezing point 16-19c
f) Initial boiling point and boiling range 6.15
g) Flash point No Data
h) Evaporation rate No Data
i) Flammability (solid, gas) No Data
j) Upper/lower flammability or explosive limits 42% (v) and 3.5% (v)
k) Vapour pressure No Data
l) Vapour density No Data
m) Relative density No Data
n) Water solubility
o) Partition coefficient: noctanol/ water No Data
p) Auto-ignitiontemperature No Data
q) Decomposition temperature 1,1 g/mL
r) Viscosity completely miscible
s) Explosive properties No
t) Oxidizing properties No Data
9.2 Other safety information Relative vapour density 2,70 - (Air = 1.0)
10. STABILITY AND REACTIVITY

10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
Heat, flames and sparks
10.5 Incompatible materials
Acid chlorides, Phosphorus halides, Strong acids, Strong oxidizing agents, Strong reducing agents
10.6 Hazardous decomposition products
Other decomposition products - No data available
In the event of fire: see section 5
11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects Acute toxicity LD50 Oral - Rat - 14.500 mg/kg LC50 Inhalation - Rat - 4 h - 40250 ppm LD50 Dermal - Rabbit - > 5.000 mg/kg
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
Mouse lymphocyte Cytogenetic analysis Mouse lymphocyte Mutation in mammalian somatic cells. Rat Cytogenetic analysis Mouse DNA damage
Carcinogenicity
Carcinogenicity - Rat - Oral Tumorigenic:Equivocal tumorigenic agent by RTECS criteria. Skin and Appendages: Other: Tumors. Carcinogenicity - Mouse - Oral Tumorigenic:Equivocal tumorigenic agent by RTECS criteria. Leukaemia Skin and Appendages: Other: Tumors. IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC..
Reproductive toxicity
Reproductive toxicity - Rat - Intraperitoneal Effects on Fertility: Abortion. Reproductive toxicity - Rat - Intraperitoneal Effects on Fertility: Post-implantation mortality (e.g., dead and/or resorbed implants per total number of implants). Reproductive toxicity - Rat - Subcutaneous Sigma - D9170 Page 6 of 7 Effects on Fertility: Post-implantation mortality (e.g., dead and/or resorbed implants per total number of implants). Effects on Fertility: Litter size (e.g.; # fetuses per litter; measured before birth). Reproductive toxicity - Mouse - Oral Effects on Fertility: Pre-implantation mortality (e.g., reduction in number of implants per female; total number of implants per corpora lutea). Effects on Embryo or Fetus: Fetotoxicity (except death, e.g., stunted fetus). Specific Developmental Abnormalities: Musculoskeletal system. Developmental Toxicity - Mouse - Intraperitoneal Effects on Embryo or Fetus: Fetotoxicity (except death, e.g., stunted fetus). Specific Developmental Abnormalities: Musculoskeletal system.
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: PV6210000 Effects due to ingestion may include:, Nausea, Fatigue, Headache To the best of our knowledge
12. ECOLOGICAL INFORMATION

12.1 Toxicity Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 34.000 mg/l - 96 h LC50 - Oncorhynchus mykiss (rainbow trout) - 35.000 mg/l - 96 h Toxicity to daphnia and other aquatic invertebrates EC50 - Daphnia magna (Water flea) - 24.600 mg/l - 48 h (OECD Test Guideline 202) Toxicity to algae EC50 - Pseudokirchneriella subcapitata (green algae) - 17.000 mg/l - 72 h (OECD Test Guideline 201)
12.2 Persistence and degradability Biodegradability Result: 31 % - According to the results of tests of biodegradability this product is not readily biodegradable. (OECD Test Guideline 301D)
12.3 Bioaccumulative potential No data available
12.4 Mobility in soil No data available
12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
12.6 Other adverse effects No data available Stability in water - 0,12 - 1,2 h at 30 C Remarks: Hydrolyses readily.
13.1 Waste treatment methods Product
This combustible material may be burned in a chemical incinerator equipped with an afterburner and scrubber. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material.
Contaminated packaging
Dispose of as unused product.
14. TRANSPORT INFORMATION DOT (US)

Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods
15. REGULATORY INFORMATION

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture No data available
15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out
16. OTHER INFORMATION

Copyright 2015 Tian jin Baofeng Chemical Co. Ltd. License granted to make unlimited paper copies for internal use only. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Baofeng-Aldrich Corporation and its Affiliates shall not be held liable for any damage resulting from handling or from contact with the above product. See www.bf-msm.com and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.



Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: BALLANCE BIOPHOS PRODUCT USE Used according to manufacturer's directions.
HAZARD RATINGS
Min Max
Flammability: 0
Toxicity: 2
Body Contact: 2
Reactivity: 0
Chronic: 4
Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4
Section 2 - HAZARDS IDENTIFICATION STATEMENT OF HAZARDOUS NATURE
NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code.
POISONS SCHEDULE None
RISK SAFETY
Ingestion may produce health damage*. Avoid exposure - obtain special instructions before use.
Cumulative effects may result following exposure*.
May produce discomfort of the respiratory system*.
Possible respiratory and skin sensitiser*.
Possible cancer-causing agent*.
* (limited evidence).
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
phosphate rocks >60
saw dust, as 1-10 wood dust softwood Not avail.
fish emulsion 1-10
additives, nonhazardous <1
Section 4 - FIRST AID MEASURES SWALLOWED
 If swallowed do NOT induce vomiting.
 If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.
 Observe the patient carefully.
 Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
 Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
 Seek medical advice.
EYE
If this product comes in contact with the eyes:
 Wash out immediately with fresh running water.
 Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.
 If pain persists or recurs seek medical attention.
 Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
SKIN If skin contact occurs:
 Immediately remove all contaminated clothing, including footwear.
 Flush skin and hair with running water (and soap if available).
 Seek medical attention in event of irritation.
INHALED
 If fumes or combustion products are inhaled remove from contaminated area.
 Other measures are usually unnecessary.
NOTES TO PHYSICIAN For acute or short term repeated exposures to fluorides:
 Fluoride absorption from gastro-intestinal tract may be retarded by calcium salts, milk or antacids.
 Fluoride particulates or fume may be absorbed through the respiratory tract with 20-30% deposited at alveolar level.
 Peak serum levels are reached 30 mins. post-exposure; 50% appears in the urine within 24 hours.
 For acute poisoning (endotracheal intubation if inadequate tidal volume), monitor breathing and evaluate/monitor blood pressure and pulse frequently since shock may supervene with little warning. Monitor ECG immediately; watch for arrhythmias and evidence of Q-T prolongation or T-wave changes. Maintain monitor. Treat shock vigorously with isotonic saline (in 5% glucose) to restore blood volume and enhance renal excretion.
 Where evidence of hypocalcaemic or normocalcaemic tetany exists, calcium gluconate (10 ml of a 10% solution) is injected to avoid tachycardia.
BIOLOGICAL EXPOSURE INDEX - BEI These represent the determinants observed in specimens collected from a healthy worker exposed at the Exposure Standard (ES or TLV):
B: Background levels occur in specimens collected from subjects NOT exposed
NS: Non-specific determinant; also observed after exposure to other exposures.
Determinant Index Sampling Time Comments Fluorides in urine 3 mg/gm creatinine Prior to shift B, NS 10mg/gm creatinine End of shift B, NS
Section 5 - FIRE FIGHTING MEASURES EXTINGUISHING MEDIA
 There is no restriction on the type of extinguisher which may be used.
 Use extinguishing media suitable for surrounding area.
FIRE FIGHTING
 Alert Fire Brigade and tell them location and nature of hazard.
 Wear breathing apparatus plus protective gloves for fire only.
 Prevent, by any means available, spillage from entering drains or water courses.
 Use fire fighting procedures suitable for surrounding area.
 DO NOT approach containers suspected to be hot.
 Cool fire exposed containers with water spray from a protected location.
 If safe to do so, remove containers from path of fire.
 Equipment should be thoroughly decontaminated after use.
FIRE/EXPLOSION HAZARD
 Non combustible.
 Not considered a significant fire risk, however containers may burn.
Decomposition may produce toxic fumes of: hydrogen fluoride, phosphorus oxides (POx). May emit poisonous fumes. May emit corrosive fumes.
FIRE INCOMPATIBILITY None known.
HAZCHEM None
Section 6 - ACCIDENTAL RELEASE MEASURES EMERGENCY PROCEDURES MINOR SPILLS
 Clean up waste regularly and abnormal spills immediately.
 Avoid breathing dust and contact with skin and eyes.
 Wear protective clothing, gloves, safety glasses and dust respirator.
 Use dry clean up procedures and avoid generating dust.
 Vacuum up or sweep up. NOTE: Vacuum cleaner must be fitted with an exhaust micro filter (HEPA type) (consider explosionproof machines designed to be grounded during storage and use).
 Dampen with water to prevent dusting before sweeping.
 Place in suitable containers for disposal.
MAJOR SPILLS
 After clean up operations, decontaminate and launder all protective clothing and equipment before storing and re-using.
SAFE STORAGE WITH OTHER CLASSIFIED CHEMICALS
+ + + + X +
X: Must not be stored together
O: May be stored together with specific preventions
+: May be stored together
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE PROCEDURE FOR HANDLING
 Avoid all personal contact, including inhalation.
 Wear protective clothing when risk of exposure occurs.
 Use in a well-ventilated area.
 Prevent concentration in hollows and sumps.
 DO NOT enter confined spaces until atmosphere has been checked.
 DO NOT allow material to contact humans, exposed food or food utensils.
 Avoid contact with incompatible materials.
 When handling, DO NOT eat, drink or smoke.
 Keep containers securely sealed when not in use.
 Avoid physical damage to containers.
 Always wash hands with soap and water after handling.
 Work clothes should be laundered separately. Launder contaminated clothing before re-use.
 Use good occupational work practice.
 Observe manufacturer's storing and handling recommendations.
 Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are maintained.
SUITABLE CONTAINER
 Polyethylene or polypropylene container.
 Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
 Contact with acids produces toxic fumes
STORAGE REQUIREMENTS
 Store in original containers.
 Keep containers securely sealed.
 Store in a cool, dry, well-ventilated area.
 Store away from incompatible materials and foodstuff containers.
 Protect containers against physical damage and check regularly for leaks.
 Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA ppm TWA mg/m STEL ppm STEL mg/m Peak ppm Peak mg/m TWA F/CC Australia Exposure Standards wood dust softwood (Wood dust (soft wood)) 5 10
MATERIAL DATA
It is the goal of the ACGIH (and other Agencies) to recommend TLVs (or their equivalent) for all substances for which there is evidence of health effects at airborne concentrations encountered in the workplace. At this time no TLV has been established, even though this material may produce adverse health effects (as evidenced in animal experiments or clinical experience). Airborne concentrations must be maintained as low as is practically possible and occupational exposure must be kept to a minimum.
NOTE: The ACGIH occupational exposure standard for Particles Not Otherwise Specified (P.N.O.S) does NOT apply. Sensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or throat. Historically occupational exposure standards for these irritants have been based on observation of workers' responses to various airborne concentrations. Present day expectations require that nearly every individual should be protected against even minor sensory irritation and exposure standards are established using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no-observable-effect-levels (NOEL) are used to determine these limits where human results are unavailable. An additional approach, typically used by the TLV committee (USA) in determining respiratory standards for this group of chemicals, has been to assign ceiling values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five-category system based on intensive odour, local irritation, and elimination half-life. However this system is being replaced to be consistent with the European Union (EU) Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely allied to that of the USA.
OSHA (USA) concluded that exposure to sensory irritants can:
 cause inflammation
 cause increased susceptibility to other irritants and infectious agents
 lead to permanent injury or dysfunction
 permit greater absorption of hazardous substances and
 acclimate the worker to the irritant warning properties of these substances thus increasing the risk of overexposure.
INGREDIENT DATA WOOD DUST SOFTWOOD:
Wood dusts produce dermatitis and an increased risk of upper respiratory disease. Epidemiological studies in furniture workers show an increased risk of lung, tongue, pharynx and nasal cancer. An excess risk of leukaemia amongst millwrights probably is associated with exposure to various components used in wood preservation. Impairment of nasal mucociliary function may occur below 5 mg/m3 and may be important in the development of nasal adenocarcinoma amongst furniture workers exposed to hardwoods. Certain exotic hardwoods contain alkaloids which may produce headache, anorexia, nausea, bradycardia and dyspnoea. The softwood TLV-TWA reflects the apparent low risk for upper respiratory tract involvement amongst workers in the building industry. A separate TLV-TWA, for hard woods, is based on impaired nasal mucociliary function reported to contribute to nasal adenocarcinoma and related hyperplasia found in furniture workers.
PERSONAL PROTECTION EYE
 Safety glasses with side shields.
 Chemical goggles.
 Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59]
HANDS/FEET
Experience indicates that the following polymers are suitable as glove materials for protection against undissolved, dry solids, where abrasive particles are not present.
 polychloroprene
 nitrile rubber
 butyl rubber
 fluorocaoutchouc
 polyvinyl chloride
Gloves should be examined for wear and/ or degradation constantly. Suitability and durability of glove type is dependent on usage. Factors such as:
 frequency and duration of contact,
 chemical resistance of glove material,
 glove thickness and
 dexterity, are important in the selection of gloves.
NOTE:  The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other protective equipment, to avoid all possible skin contact.
 Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.
OTHER
 Overalls.
 P.V.C. apron.
 Barrier cream.
 Skin cleansing cream.
 Eye wash unit.
 Employees working with confirmed human carcinogens should be provided with, and be required to wear, clean, full body protective clothing (smocks, coveralls, or long-sleeved shirt and pants), shoe covers and gloves prior to entering the regulated area.
 Employees engaged in handling operations involving carcinogens should be provided with, and required to wear and use halfface filter-type respirators with filters for dusts, mists and fumes, or air purifying canisters or cartridges. A respirator affording higher levels of protection may be substituted.
 Emergency deluge showers and eyewash fountains, supplied with potable water, should be located near, within sight of, and on the same level with locations where direct exposure is likely.
 Prior to each exit from an area containing confirmed human carcinogens, employees should be required to remove and leave protective clothing and equipment at the point of exit and at the last exit of the day, to place used clothing and equipment in impervious containers at the point of exit for purposes of decontamination or disposal. The contents of such impervious containers must be identified with suitable labels. For maintenance and decontamination activities, authorized employees entering the area should be provided with and required to wear clean, impervious garments, including gloves, boots and continuous-air supplied hood.
 Prior to removing protective garments the employee should undergo decontamination and be required to shower upon removal of the garments and hood.
RESPIRATOR
* - Negative pressure demand ** - Continuous flow.
The local concentration of material, quantity and conditions of use determine the type of personal protective equipment required.
For further information consult site specific CHEMWATCH data (if available), or your Occupational Health and Safety Advisor.
Protection Factor Half-Face Respirator Full-Face Respirator Powered Air Respirator
10 x ES P1 Air-line* - - PAPR-P1 -
50 x ES Air-line** P2 PAPR-P2
100 x ES - P3 -
Air-line* -
100+ x ES - Air-line** PAPR-P3
ENGINEERING CONTROLS
 Employees exposed to confirmed human carcinogens should be authorized to do so by the employer, and work in a regulated area.
 Work should be undertaken in an isolated system such as a "glove-box" . Employees should wash their hands and arms upon completion of the assigned task and before engaging in other activities not associated with the isolated system.
 Within regulated areas, the carcinogen should be stored in sealed containers, or enclosed in a closed system, including piping systems, with any sample ports or openings closed while the carcinogens are contained within.
 Open-vessel systems are prohibited.
 Each operation should be provided with continuous local exhaust ventilation so that air movement is always from ordinary work areas to the operation.
 Exhaust air should not be discharged to regulated areas, non-regulated areas or the external environment unless decontaminated. Clean make-up air should be introduced in sufficient volume to maintain correct operation of the local exhaust system.
 For maintenance and decontamination activities, authorized employees entering the area should be provided with and required to wear clean, impervious garments, including gloves, boots and continuous-air supplied hood. Prior to removing protective garments the employee should undergo decontamination and be required to shower upon removal of the garments and hood.
 Except for outdoor systems, regulated areas should be maintained under negative pressure (with respect to non-regulated areas).
 Local exhaust ventilation requires make-up air be supplied in equal volumes to replaced air.
 Laboratory hoods must be designed and maintained so as to draw air inward at an average linear face velocity of 150 feet/ min. with a minimum of 125 feet/ min. Design and construction of the fume hood requires that insertion of any portion of the employees body, other than hands and arms, be disallowed.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE
Light fawn to brown powders; does not mix with water.
PHYSICAL PROPERTIES Does not mix with water. Sinks in water.
Molecular Weight: Not Applicable Boiling Range (C): Not Applicable
Melting Range (C): Not Available Specific Gravity (water=1): 1.2
Solubility in water (g/L): Immiscible pH (as supplied): Not Applicable
pH (1% solution): Not Applicable Vapour Pressure (kPa): Not Available
Volatile Component (%vol): Not Available Evaporation Rate: Not Applicable
Relative Vapour Density (air=1): Not Applicable Flash Point (C): Not Applicable
Lower Explosive Limit (%): Not Applicable Upper Explosive Limit (%): Not Applicable
Autoignition Temp (C): Not Available Decomposition Temp (C): Not Available
State: Divided Solid Viscosity: Not Available
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION CONDITIONS CONTRIBUTING TO INSTABILITY
 Presence of incompatible materials.
 Product is considered stable.
 Hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION POTENTIAL HEALTH EFFECTS ACUTE HEALTH EFFECTS
SWALLOWED Accidental ingestion of the material may be damaging to the health of the individual. Fluoride causes severe loss of calcium in the blood, with symptoms appearing several hours later including painful and rigid muscle contractions of the limbs. Cardiovascular collapse can occur and may cause death with increased heart rate and other heart rhythm irregularities. The brain and kidneys may be affected. Other toxic effects include headache, increased saliva output, jerking of the eyeball and dilated pupils, lethargy, stupor, coma and rarely, convulsions.
EYE Although the material is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may cause transient discomfort characterised by tearing or conjunctival redness (as with windburn). Slight abrasive damage may also result. The material may produce foreign body irritation in certain individuals.
SKIN Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected. The material is not thought to produce adverse health effects or skin irritation following contact (as classified by EC Directives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable gloves be used in an occupational setting.
INHALED Not normally a hazard due to non-volatile nature of product. Persons with impaired respiratory function, airway diseases and conditions such as emphysema or chronic bronchitis, may incur further disability if excessive concentrations of particulate are inhaled. Acute effects of fluoride inhalation include irritation of nose and throat, coughing and chest discomfort. A single acute overexposure may even cause nose bleed. Pre-existing respiratory conditions such as emphysema, bronchitis may be aggravated by exposure. Occupational asthma may result from exposure.
CHRONIC HEALTH EFFECTS Long term exposure to high dust concentrations may cause changes in lung function i.e. pneumoconiosis; caused by particles less than 0.5 micron penetrating and remaining in the lung. Prime symptom is breathlessness; lung shadows show on X-ray. Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure. There is some evidence that inhaling this product is more likely to cause a sensitisation reaction in some persons compared to the general population. There is limited evidence that, skin contact with this product is more likely to cause a sensitisation reaction in some persons compared to the general population. There is sufficient evidence to suggest that this materialdirectly causes cancer in humans. Various woods are able to induce allergies, both of the immediate onset type in woodwork which causes a respiratory syndrome, and of the delayed type which results in eczema from exposure to dusts and direct contact. Cross-reaction is common. Certain alkaloids are contained in some species, causing headache, anorexia, slow heart rate and breathing difficulties. Conjunctivitis is also possible. Allergic reactions are aggravated by fungi and bacteria associated with wood. Cancers of the respiratory tract seem to be more common in those professions associated with the use of wood. This seems to be true for both hardwood and soft wood.
TOXICITY AND IRRITATION
Not available. Refer to individual constituents. Section 12 - ECOLOGICAL INFORMATION
DO NOT discharge into sewer or waterways.
Refer to data for ingredients, which follows:
WOOD DUST SOFTWOOD:
Section 13 - DISPOSAL CONSIDERATIONS
 Recycle wherever possible or consult manufacturer for recycling options.
 Consult State Land Waste Management Authority for disposal.
 Bury residue in an authorised landfill.
 Recycle containers if possible, or dispose of in an authorised landfill.
 Containers may still present a chemical hazard/ danger when empty.
 Return to supplier for reuse/ recycling if possible.
Otherwise:
 If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.
 Where possible retain label warnings and MSDS and observe all notices pertaining to the product.
Section 14 - TRANSPORTATION INFORMATION
HAZCHEM: None (ADG6)
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: UN, IATA, IMDG
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE None
REGULATIONS Ballance BioPhos (CAS: None):
No regulations applicable
wood dust softwood (CAS:Not avail): No regulations applicable
No data available for wood dust softwood as CAS: Not avail.
Section 16 - OTHER INFORMATION
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references. A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered. This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 3-Apr-2007 Print Date:18-Jun-2016

Wallys Fruit and Flower Power:

This is 60% Sulfate of Potash and 40% Magnesium Sulfate:
The MSDs for both these fertilisers are a accurate description of the product.
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME
SULFATE OF POTASH
STATEMENT OF HAZARDOUS NATURE
Not considered a Hazardous Substance according to the criteria of the New Zealand Hazardous Substances New Organisms legislation.
OTHER NAMES
K2-S-O4, K2-S-O4, "potassium sulphate", "sulfate of potash", "sulphate of potash", "sulphuric acid", "sulfuric acid, dipotassium salt", "kalium sulfuricum"
PRODUCT USE
Fertiliser.
SUPPLIER

Company: Ballance Agri-Nutrients Limited
Address:
Hewletts Road
Mount Maunganui
New Zealand
Telephone: 07 572 7900
Emergency Tel: 00800 2436 2255
Emergency Tel: 00613 9573 3112
Fax: 07 575 6233
HAZARD RATINGS
Min Max
Flammability: 0
Toxicity: 2
Body Contact: 1
Reactivity: 0
Chronic: 0
Min/Nil=0
Low=1
Moderate=2
High=3
Extreme=4
Section 2 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
HAZARD
Not hazardous
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
potassium sulfate 7778-80-5 >60
Section 4 - FIRST AID MEASURES
SWALLOWED
 If swallowed do NOT induce vomiting.
 If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.
 Observe the patient carefully.
 Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.

 Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
 Seek medical advice.
EYE If this product comes in contact with the eyes:
 Wash out immediately with fresh running water.
 Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.
 If pain persists or recurs seek medical attention.
 Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
SKIN If skin or hair contact occurs:
 Flush skin and hair with running water (and soap if available).
 Seek medical attention in event of irritation.
INHALED  If dust is inhaled, remove from contaminated area.
 Encourage patient to blow nose to ensure clear passage of breathing.
 If irritation or discomfort persists seek medical attention.
NOTES TO PHYSICIAN For potassium intoxications:
 Hyperkalaemia, in patients with abnormal renal function, results from reduced renal excretion following intoxication.
 The presence of electrocardiographic evidence of hyperkalemia or serum potassium levels exceeding 7.5 mE/L indicates a medical emergency requiring an intravenous line and constant cardiac monitoring.
 The intravenous ingestion of 5-10 ml of 10% calcium gluconate, in adults, over a 2 minute period antagonises the cardiac and neuromuscular effects. The duration of action is approximately 1 hour. [Ellenhorn and Barceloux: Medical Toxicology]
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
 There is no restriction on the type of extinguisher which may be used.
 Use extinguishing media suitable for surrounding area.
FIRE FIGHTING Alert Fire Brigade and tell them location and nature of hazard.
 Wear breathing apparatus plus protective gloves.
 Prevent, by any means available, spillage from entering drains or water courses.
Use fire fighting procedures suitable for surrounding area. DO NOT approach containers suspected to be hot. If safe to do so, remove containers from path of fire.
FIRE/EXPLOSION HAZARD
 Non combustible.
 Not considered a significant fire risk, however containers may burn.
Decomposes on heating and produces toxic fumes of: sulfur oxides (SOx).
Section 6 - ACCIDENTAL RELEASE MEASURES MINOR SPILLS
 Clean up all spills immediately.
 Avoid contact with skin and eyes.
 Wear impervious gloves and safety glasses.
 Use dry clean up procedures and avoid generating dust.
 Vacuum up (consider explosion-proof machines designed to be grounded during storage and use).
 Do NOT use air hoses for cleaning
 Place spilled material in clean, dry, sealable, labelled container.
MAJOR SPILLS
 Clear area of personnel and move upwind.
 Alert Fire Brigade and tell them location and nature of hazard.
 Control personal contact by using protective equipment and dust respirator.
 Prevent spillage from entering drains, sewers or water courses.
 Avoid generating dust.
 Sweep, shovel up. Recover product wherever possible.
 Put residues in labelled plastic bags or other containers for disposal.
 If contamination of drains or waterways occurs, advise emergency services.
SAFE STORAGE WITH OTHER CLASSIFIED CHEMICALS
+ + + + X +
X: Must not be stored together
O: May be stored together with specific preventions
+: May be stored together
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE PROCEDURE FOR HANDLING
 Limit all unnecessary personal contact.
 Wear protective clothing when risk of exposure occurs.
 Use in a well-ventilated area.
 When handling DO NOT eat, drink or smoke.
 Always wash hands with soap and water after handling.
 Avoid physical damage to containers.
 Use good occupational work practice.
 Observe manufacturer's storing and handling recommendations.
SUITABLE CONTAINER Multi-ply woven plastic or paper bag with sealed plastic liner NOTE: Bags should be stacked, blocked, interlocked, and limited in height so that they are stable and secure against sliding or collapse.
STORAGE INCOMPATIBILITY Segregate from active metals such as aluminium and magnesium.
STORAGE REQUIREMENTS
 Keep dry.
 Store in original containers.
 Keep containers securely sealed.
 No smoking, naked lights or ignition sources.
 Store in a cool, dry, well-ventilated area.
 Store away from incompatible materials.
 Protect containers against physical damage.
 Check regularly for leaks.
 Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
The following materials had no OELs on our records
potassium sulfate: CAS:7778-80-5
MATERIAL DATA Not available. Refer to individual constituents.
INGREDIENT DATA POTASSIUM SULFATE:
It is the goal of the ACGIH (and other Agencies) to recommend TLVs (or their equivalent) for all substances for which there is evidence of health effects at airborne concentrations encountered in the workplace.
At this time no TLV has been established, even though this material may produce adverse health effects (as evidenced in animal experiments or clinical experience). Airborne concentrations must be maintained as low as is practically possible and occupational exposure must be kept to a minimum.
NOTE: The ACGIH occupational exposure standard for Particles Not Otherwise Specified (P.N.O.S) does NOT apply.
PERSONAL PROTECTION
EYE
 Safety glasses with side shields; or as required,
 Chemical goggles.
 Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59]
HANDS/FEET
Wear protective gloves, eg. PVC.
OTHER
 Overalls.
 Eyewash unit.
RESPIRATOR
* - Negative pressure demand ** - Continuous flow. The local concentration of material, quantity and conditions of use determine the type of personal protective equipment required. For further information consult site specific CHEMWATCH data (if available), or your Occupational Health and Safety Advisor.
Protection Factor Half-Face Respirator Full-Face Respirator Powered Air Respirator
10 x ES P1 Air-line* - - PAPR-P1 -
50 x ES Air-line** P2 PAPR-P2
100 x ES - P3 -
Air-line* -
100+ x ES - Air-line** PAPR-P3
ENGINEERING CONTROLS General exhaust is adequate under normal operating conditions. If risk of overexposure exists, wear SAA approved respirator. Correct fit is essential to obtain adequate protection. Provide adequate ventilation in warehouse or closed storage areas. Air contaminants generated in the workplace possess varying "escape" velocities which, in turn, determine the "capture velocities" of fresh circulating air required to effectively remove the contaminant. Within each range the appropriate value depends on: Simple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction pipe. Velocity generally decreases with the square of distance from the extraction point (in simple cases). Therefore the air speed at the extraction point should be adjusted, accordingly, after reference to distance from the contaminating source. The air velocity at the extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min.) for extraction of solvents generated in a tank 2 meters distant from the extraction point. Other mechanical considerations, producing performance deficits within the extraction apparatus, make it essential that theoretical air velocities are multiplied by factors of 10 or more when extraction systems are installed or used. Type of Contaminant: Air Speed: solvent, vapours, degreasing etc., evaporating from tank (in still air) 0.25-0.5 m/s (50-100 f/min) aerosols, fumes from pouring operations, intermittent container filling, low speed conveyer transfers, welding, spray drift, plating acid fumes, pickling (released at low velocity into zone of active generation) 0.5-1 m/s (100-200 f/min.) direct spray, spray painting in shallow booths, drum filling, conveyer loading, crusher dusts, gas discharge (active generation into zone of rapid air motion) 1-2.5 m/s (200-500 f/min) grinding, abrasive blasting, tumbling, high speed wheel generated dusts (released at high initial velocity into zone of very high rapid air motion). 2.5-10 m/s (500-2000 f/min.) Lower end of the range Upper end of the range 1: Room air currents minimal or favourable to capture 1: Disturbing room air currents 2: Contaminants of low toxicity or of nuisance value only 2: Contaminants of high toxicity 3: Intermittent, low production. 3: High production, heavy use 4: Large hood or large air mass in motion 4: Small hood - local control only
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
White, odourless, crystals; soluble in water.
PHYSICAL PROPERTIES Solid.
Mixes with water.
Molecular Weight: Not applicable Boiling Range (C): 1689
Melting Range (C): 1069 Specific Gravity (water=1): 2.7 approx.
Solubility in water (g/L): Miscible pH (as supplied): Not applicable
pH (1% solution): Not available Vapour Pressure (kPa): Not applicable
Volatile Component (%vol): Not applicable Evaporation Rate: Not applicable
Relative Vapour Density (air=1): Not applicable Flash Point (C): Not applicable
Lower Explosive Limit (%): Not applicable Upper Explosive Limit (%): Not applicable
Autoignition Temp (C): Not applicable Decomposition Temp (C): Not available
State: Divided solid Viscosity: Not available
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
 Presence of incompatible materials.
 Product is considered stable.
 Hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS ACUTE HEALTH EFFECTS SWALLOWED
The material is moderately discomforting to the gastro-intestinal tract and may be harmful if swallowed in large quantity. Sulfates are not well absorbed orally, but can cause diarrhoea. Acute potassium poisoning after swallowing is rare, because vomiting usually occurs and renal excretion is fast. Potassium causes a slow, weak pulse, irregularities in heart rhythm, heart block and an eventual fall in blood pressure. Breathing initially becomes faster but the muscles of breathing eventually become paralysed. There can be loss of appetite, extreme thirst, increased volumes of urine, fever, convulsions and gastric disturbances; death may then occur due to failure of breathing and inflammation of the stomach and bowel.
EYE The dust may produce eye discomfort causing smarting, pain and redness.
SKIN The material may be mildly discomforting to the skin. Open cuts, abraded or irritated skin should not be exposed to this material. The material may accentuate any pre-existing skin condition.
INHALED The dust may be discomforting to the upper respiratory tract. Persons with impaired respiratory function, airway diseases and conditions such as emphysema or chronic bronchitis, may incur further disability if excessive concentrations of particulate are inhaled.
CHRONIC HEALTH EFFECTS Principal routes of exposure are by accidental skin and eye contact and inhalation of generated dusts. No human exposure data available. For this reason health effects described are based on experience with chemically related materials. As with any chemical product, contact with unprotected bare skin; inhalation of vapour, mist or dust in work place atmosphere; or ingestion in any form, should be avoided by observing good occupational work practice.
TOXICITY AND IRRITATION Not available. Refer to individual constituents.
POTASSIUM SULFATE: unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: 6600 mg/kg Nil Reported
Section 12 - ECOLOGICAL INFORMATION
Refer to data for ingredients, which follows:
POTASSIUM SULFATE:
Section 13 - DISPOSAL CONSIDERATIONS
 Recycle wherever possible or consult manufacturer for recycling options.
 Consult State Land Waste Management Authority for disposal.
 Bury residue in an authorised landfill.
 Recycle containers if possible, or dispose of in an authorised landfill.
Section 14 - TRANSPORTATION INFORMATION
HAZCHEM: None
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: UN, IATA, IMDG
Section 15 - REGULATORY INFORMATION
REGULATIONS Regulations for ingredients Sulfate of Potash (CAS: None):
No regulations applicable potassium sulfate (CAS: 7778- 80- 5) is found on the following regulatory lists; CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP
International Council of Chemical Associations (ICCA) - High Production Volume List
New Zealand Hazardous Substances and New Organisms (HSNO) Act - Chemicals (single components)
New Zealand Inventory of Chemicals (NZIoC)
OECD Representative List of High Production Volume (HPV) Chemicals
Specific advice on controls required for materials used in New Zealand can be found at http://www.ermanz.govt.nz/search/registers.html
Section 16 - OTHER INFORMATION
NEW ZEALAND POISONS INFORMATION CENTRE
0800 POISON (0800 764 766)
NZ EMERGENCY SERVICES: 111
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered. This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 25-Aug-2008
Print Date:12-Jun-2016
SULFATE OF POTASH Hazard Alert Code: MODERATE
Chemwatch Material Safety Data Sheet (REVIEW) Revision No: 4 Chemwatch 4803-38
Issue Date: 25-Aug-2015 CD 2009/1


Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME KIESERITE
STATEMENT OF HAZARDOUS NATURE Not considered a Hazardous Substance according to the criteria of the New Zealand Hazardous Substances New Organisms legislation.
OTHER NAMES MgSO4, "magnesium sulfate", "anhydrous magnesium sulphate", "sulfuric acid, magnesium salt(1:1)", "dried epsom salts"
PRODUCT USE Fertiliser.
SUPPLIER Company: Ballance Agri-Nutrients Limited
Address: Hewletts Road
Mount Maunganui
New Zealand
Telephone: 07 572 7900
Emergency Tel: 00800 2436 2255
Emergency Tel: 00613 9573 3112
Fax: 07 575 6233
HAZARD RATINGS
Min Max
Flammability: 0
Toxicity: 2
Body Contact: 2
Reactivity: 0
Chronic: 0
Min/Nil=0
Low=1
Moderate=2
High=3
Extreme=4
Section 2 - HAZARDS IDENTIFICATION
GHS Classification
Eye Irritation Category 2B
EMERGENCY OVERVIEW
HAZARD WARNING
Determined by Chemwatch using GHS/HSNO criteria:
6.4A
Causes eye irritation
PRECAUTIONARY STATEMENTS
Prevention Wash thoroughly after handling. Response
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
magnesium sulfate, anhydrous 7487-88-9 >60
Section 4 - FIRST AID MEASURES
SWALLOWED
KIESERITE Hazard Alert Code:
MODERATE
 Immediately give a glass of water.
 First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
EYE If this product comes in contact with the eyes:
 Wash out immediately with fresh running water.
 Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.
 If pain persists or recurs seek medical attention.
 Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
SKIN If skin or hair contact occurs:
 Flush skin and hair with running water (and soap if available).
 Seek medical attention in event of irritation.
INHALED
 If fumes or combustion products are inhaled remove from contaminated area.
 Lay patient down. Keep warm and rested.
 Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
 Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
 Transport to hospital, or doctor.
NOTES TO PHYSICIAN Magnesium is present in the blood, as a normal constituent, at concentrations between 1.6 to 2.2 meq/l. Some 30% is plasma bound. At serum magnesium levels of 3-4 mEq/l, signs of CNS depression, loss of reflexes, muscular tone and power, and bradycardia occur. Cardiac arrest (sometimes fatal) and/or respiratory paralysis can occur at plasma levels of 10-15 meq/l. For acute or short term repeated exposures to magnesium;
 Symptomatic hypermagnesaemia appears rarely in the absence of intestinal or renal disease.
 Elevated magnesium levels may cause hypocalcaemia because of decreased parathyroid hormone activity and decreased endorgan responsiveness.
 Patients with severe hypermagnesemia may develop sudden respiratory arrest and must be watched closely for apnoea.

 Use fluids, then vasopressors for hypotension. Frequently hypotension responds to calcium administration.  Induce emesis or administer lavage if patient presents within 4 hours of ingestion. Use sodium cathartics, with caution, in presence of cardiac or renal failure.
 Activated charcoal is not useful.
 Calcium is an antagonist of magnesium action and is an effective antidote when serum levels exceed 5MEg/L and the patient exhibits symptoms The adult dose of calcium gluconate is 10 ml of a 10% solution over several minutes. [Ellenhorn and Barceloux: Medical Toxicology]
Section 5 - FIRE FIGHTING MEASURES EXTINGUISHING MEDIA
 There is no restriction on the type of extinguisher which may be used.
Use fire fighting procedures suitable for surrounding area.
FIRE FIGHTING
 Alert Fire Brigade and tell them location and nature of hazard.
 Wear breathing apparatus plus protective gloves for fire only.
 Prevent, by any means available, spillage from entering drains or water courses.
 Use fire fighting procedures suitable for surrounding area.
 DO NOT approach containers suspected to be hot.
 Cool fire exposed containers with water spray from a protected location.
 If safe to do so, remove containers from path of fire.
 Equipment should be thoroughly decontaminated after use.
FIRE/EXPLOSION HAZARD
 Non combustible.
 Not considered a significant fire risk, however containers may burn.
Decomposes on heating and produces toxic fumes of: sulfur oxides (SOx).
FIRE INCOMPATIBILITY None known.
Section 6 - ACCIDENTAL RELEASE MEASURES MINOR SPILLS
 Clean up all spills immediately.
 Avoid contact with skin and eyes.
 Wear impervious gloves and safety glasses.
 Use dry clean up procedures and avoid generating dust.
 Vacuum up (consider explosion-proof machines designed to be grounded during storage and use).
 Do NOT use air hoses for cleaning
 Place spilled material in clean, dry, sealable, labelled container.
MAJOR SPILLS
 Clear area of personnel and move upwind.
 Alert Fire Brigade and tell them location and nature of hazard.
 Control personal contact by using protective equipment and dust respirator.
 Prevent spillage from entering drains, sewers or water courses.
 Recover product wherever possible. Avoid generating dust.
 Sweep / shovel up.
 If required, wet with water to prevent dusting.
 Put residues in labelled plastic bags or other containers for disposal.
 Wash area down with large quantity of water and prevent runoff into drains.
 If contamination of drains or waterways occurs, advise emergency services.
SAFE STORAGE WITH OTHER CLASSIFIED CHEMICALS
+ + + + X +
X: Must not be stored together
O: May be stored together with specific preventions
+: May be stored together
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE PROCEDURE FOR HANDLING
 Limit all unnecessary personal contact.
 Wear protective clothing when risk of exposure occurs.
 Use in a well-ventilated area.
 When handling DO NOT eat, drink or smoke.
 Always wash hands with soap and water after handling.
 Avoid physical damage to containers.
 Use good occupational work practice.
 Observe manufacturer's storing and handling recommendations.
SUITABLE CONTAINER
 Plastic bag
 NOTE: Bags should be stacked, blocked, interlocked, and limited in height so that they are stable and secure against sliding or collapse.
 Check that containers are clearly labelled
STORAGE INCOMPATIBILITY None known.
STORAGE REQUIREMENTS
 Keep dry
 Store in original containers.
 Keep containers securely sealed.
 Store in a cool, dry, well-ventilated area.
 Store away from incompatible materials and foodstuff containers.
 Protect containers against physical damage and check regularly for leaks.
 Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
The following materials had no OELs on our records
magnesium sulfate, anhydrous: CAS:7487-88-9
MATERIAL DATA Not available. Refer to individual constituents.
INGREDIENT DATA MAGNESIUM SULFATE, ANHYDROUS:
It is the goal of the ACGIH (and other Agencies) to recommend TLVs (or their equivalent) for all substances for which there is evidence of health effects at airborne concentrations encountered in the workplace. At this time no TLV has been established, even though this material may produce adverse health effects (as evidenced in animal experiments or clinical experience). Airborne concentrations must be maintained as low as is practically possible and occupational exposure must be kept to a minimum. NOTE: The ACGIH occupational exposure standard for Particles Not Otherwise Specified (P.N.O.S) does NOT apply. Sensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or throat. Historically occupational exposure standards for these irritants have been based on observation of workers' responses to various airborne concentrations. Present day expectations require that nearly every individual should be protected against even minor sensory irritation and exposure standards are established using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no-observable-effect-levels (NOEL) are used to determine these limits where human results are unavailable. An additional approach, typically used by the TLV committee (USA) in determining respiratory standards for this group of chemicals, has been to assign ceiling values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five-category system based on intensive odour, local irritation, and elimination half-life. However this system is being replaced to be consistent with the European Union (EU) Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely allied to that of the USA. OSHA (USA) concluded that exposure to sensory irritants can:
 cause inflammation
 cause increased susceptibility to other irritants and infectious agents
 lead to permanent injury or dysfunction
 permit greater absorption of hazardous substances and
 acclimate the worker to the irritant warning properties of these substances thus increasing the risk of overexposure.
PERSONAL PROTECTION EYE
 Safety glasses with side shields; or as required,
 Chemical goggles.
 Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59]
HANDS/FEET Wear general protective gloves, eg. light weight rubber gloves.
OTHER No special equipment needed when handling small quantities OTHERWISE:
 Overalls
 Eyewash unit.
RESPIRATOR * - Negative pressure demand ** - Continuous flow.
The local concentration of material, quantity and conditions of use determine the type of personal protective equipment required. For further information consult site specific CHEMWATCH data (if available), or your Occupational Health and Safety Advisor. Protection Factor Half-Face Respirator Full-Face Respirator Powered Air Respirator 10 x ES P1 Air-line* - - PAPR-P1 -
50 x ES Air-line** P2 PAPR-P2
100 x ES - P3 -
Air-line* - 100+ x ES - Air-line** PAPR-P3
ENGINEERING CONTROLS General exhaust is adequate under normal operating conditions. If exposure to workplace dust is not controlled, respiratory protection is required; wear SAA approved dust respirator.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Off white crystals; soluble in water
PHYSICAL PROPERTIES Solid. Mixes with water. Molecular Weight: Not applicable Boiling Range (C): Not available
Melting Range (C): 1100 decomp. Specific Gravity (water=1): 2.6 approx.
Solubility in water (g/L): Miscible pH (as supplied): Not applicable
pH (1% solution): Not available Vapour Pressure (kPa): Not applicable
Volatile Component (%vol): Not applicable Evaporation Rate: Not applicable
Relative Vapour Density (air=1): Not applicable Flash Point (C): Non flammable
Lower Explosive Limit (%): Not applicable Upper Explosive Limit (%): Not applicable
Autoignition Temp (C): Not available Decomposition Temp (C): Not available
State: Divided solid Viscosity: Not available
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION CONDITIONS CONTRIBUTING TO INSTABILITY Product is considered stable and hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION POTENTIAL HEALTH EFFECTS ACUTE HEALTH EFFECTS SWALLOWED
The material is moderately discomforting to the gastro-intestinal tract and may be harmful if swallowed in large quantity. Small amounts or low dose rates are regarded as practically non-harmful. Sulfates are not well absorbed orally, but can cause diarrhoea. Magnesium salts are generally absorbed so slowly that oral administration causes few toxic effects, as the dose is readily expelled via the bowel. If evacuation fails, mucosal irritation and absorption may result. This can result in nervous system depression, heart effects, loss of reflexes and death due to paralysis of breathing. These usually do not occur unless the bowel or kidneys are damaged.
EYE The dust may produce eye discomfort and abrasive eye inflammation.
SKIN The material may be slightly discomforting to the skin if exposure is prolonged.
INHALED The dust may be discomforting to the upper respiratory tract. Persons with impaired respiratory function, airway diseases and conditions such as emphysema or chronic bronchitis, may incur further disability if excessive concentrations of particulate are inhaled.
CHRONIC HEALTH EFFECTS Principal routes of exposure are by accidental skin and eye contact and inhalation of generated dusts.
TOXICITY AND IRRITATION Not available. Refer to individual constituents.
MAGNESIUM SULFATE, ANHYDROUS: unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION Oral (man) TDLo: 428 mg/kg Nil Reported
Oral (mouse) LDLo: 5000 mg/kg
Intravenous (woman) LDLo: 80 mg/kg/2m-I
Section 12 - ECOLOGICAL INFORMATION
Refer to data for ingredients, which follows:
MAGNESIUM SULFATE, ANHYDROUS: Section 13 - DISPOSAL CONSIDERATIONS Recycle wherever possible.
Bury residue in an authorised landfill. Recycle containers if possible, or dispose of in an authorised landfill.
Section 14 - TRANSPORTATION INFORMATION HAZCHEM: None
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: UN, IATA, IMDG Section 15 - REGULATORY INFORMATION REGULATIONS Regulations for ingredients Kieserite (CAS: None):
No regulations applicable magnesium sulfate, anhydrous (CAS: 7487- 88- 9) is found on the following regulatory lists; New Zealand Inventory of Chemicals (NZIoC) OECD Representative List of High Production Volume (HPV) Chemicals Specific advice on controls required for materials used in New Zealand can be found at http://www.ermanz.govt.nz/search/registers.html
Section 16 - OTHER INFORMATION
NEW ZEALAND POISONS INFORMATION CENTRE 0800 POISON (0800 764 766)
NZ EMERGENCY SERVICES: 111
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references. A list of reference resources used to assist the committee may be found at: www.chemwatch.net/references.
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered. This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 25-Aug-2008
Print Date:12-Jun-2016
KIESERITE Hazard Alert Code:
MODERATE
Chemwatch Material Safety Data Sheet (REVIEW) Revision No: 4 Chemwatch 6548-11
Issue Date: 25-Aug-2008 CD 2009/1

Rok Solid

MATERIAL SAFETY DATA SHEET Version 2, 11 May 2009

1. IDENTIFICATION

100 % Natural Fertilisers, BioGro certified input for Organics 591
Product type: Rok Solid, Rok et Lime, Oceans 100
Fields of use: Fertiliser
Suggested methods of application: Vicon type spreader with 3 point linkage, bulk spreader (big truck or orchard spreader, Belt, chain etc), fixed wing plane. Backpack sprayer, boom spray of fieldjet off 3 point linkage sprayer, c-dax sprayer on quad bike, helicopter. Agrissentials NZ Limited
122 Lochhead Rd
RD 6
Te Puna
Tauranga 3176
Ph 07 552 4343 or
0800 843 539
Fax 07 552 4383
2. INFORMATION ON INGREDIENTS
ANALYSIS - (av.) ROK Solid: Organic 100: Ess Req for Plants
Nitrogen [N] .15% 1.5% 1.5%
Phosphorus [P] .8% 1.0% .2%
Potassium [K] 1.4% 1.0% 1.0%
Sulphur [S] .14% 2.0% .1%
Calcium [Ca] 4.4% 5.0% .5%
Magnesium [Mg] 5.69% 4.0% .2%
Sodium [Na] 2.95% 2.0% .3%
Silica [Si] 27% - 2 ppm
Iron [Fe] 3.9% 75 ppm 75 ppm
Manganese [Mn] 1,100 ppm 5 ppm 50 ppm
Boron [B] 55 ppm 18 ppm 10 ppm
Copper [Cu] 90 ppm 14 ppm 6 ppm
Zinc [Zn] 142 ppm 9 ppm 10 ppm
Cobalt [Co] 59 ppm 1 ppm 1 ppm
Molybdenum[Mo] 2 ppm 1 ppm .01 ppm
Selenium [Se] 3 ppm 1 ppm 1 ppm
Chromium [Cr] 1 ppm 6 ppm -
Non Toxic Nutrients, Minerals and water make up the balance.
The above figures are an average of analysis performed by Brookside Laboratories Inc, USA, Acadian Sea Plants Ltd, Nova Scotia, RJ Hill Laboratories Ltd, Hamilton NZ and SpectraChem Analytical Ltd, Wellington NZ
3. HAZARDS IDENTIFICATION

This product is not classified as dangerous for supply, but should not be contaminated with any product with a pH below 7 as it may produce hazardous decomposition products such as carbon monoxide, carbon dioxide and methane.
4. FIRST-AID MEASURES

General: In all cases of doubt or when symptoms persist seek medical attention and show this data sheet. Never give anything by mouth to an unconscious person.
Inhalation: In relation to point 3, remove to fresh air, keep the patient warm and at rest. If breathing has stopped, administer artificial respiration. Give nothing by mouth. If unconscious place in a prone position with head to the side (recovery position) and seek medical advice.
Eyes: In case of dust particles in the eyes, contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart. Seek medical advice if irritation persists.
Skin: Not known skin irritant. In the unlikely event of a skin irritation occuring, remove contaminated clothing. Wash skin thoroughly with soap and water or use a proprietary skin cleanser. Do NOT use white spirit, thinners or other solvents.
Ingestion: No known problems with ingestion, if accidentally swallowed obtain medical attention if symptoms occur.
5. FIRE-FIGHTING MEASURES

Specific Hazards: Non-combustible material.
Fire-Fighting advice: Non-combustible material.
6. ACCIDENTAL RELEASE MEASURES

Product not classified as dangerous, standard safety practises apply. Sweep up, but avoid generating dust. Collect into properly labelled containers (avoid breathing dust and vapours - see point 3 above).
7. HANDLING AND STORAGE

Handling: Avoid skin and eye contact. Avoid inhalation of dust, vapour and mist.
Never use pressure to empty; the container is not a pressure vessel.
Storage: Store under cover in a dry, well-ventilated place away from sources of heat and direct sunlight.
Prevent unauthorised access. Containers which are opened should be properly resealed and kept upright to prevent leakage.
Store separately from products that are below a pH of 7.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Controls: Learn the symptoms of carbon monoxide poisoning: headache, nausea, weakness, dizziness, visual disturbance and loss of consciousness.
Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and vapour below the occupational exposure limit, suitable respiratory protection must be worn.
Occupational Exposure Controls: All personal protective equipment, including respiratory protective equipment, used to control exposure dust and vapours should be used where necessary.
Respiratory protection: If exposure to dust and vapours identified above cannot be controlled by the provision of local exhaust ventilation and good general extraction, suitable respiratory protective equipment should be worn. Suitable respiratory protective equipment should be worn during spray application to prevent inhalation of spray mists.
Eye protection: Safety eyewear designed to protect against liquid splashes should be worn.
Skin Protection: Personnel should wear protective clothing. Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner.
ALWAYS WASH YOUR HANDS BEFORE EATING, SMOKING OR USING THE TOILET.
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Powder Liquid
Colour Grey Brown
Odour Earthy Strong
Specific gravity: (Kg/l) 1.6 1
10. STABILITY AND REACTIVITY

Stable under recommended storage and handling conditions (see section 7). When exposed to substances with pH below 7 these products may produce hazardous decomposition products such as carbon monoxide, carbon dioxide and methane. Keep away from acidic materials in order to avoid reactions. Not to be blended or contaminated with chemical fertilisers.
11. TOXICOLOGICAL INFORMATION

There is no data available on the product itself.
Splashes in the eye may cause irritation.
Ingestion may result in undesirable side effects such as: sore throat, nausea and vomiting.
Vapours caused by contamination with products with a pH below 7 may cause hazardous decomposition such as carbon monoxide, carbon dioxide and methane.
12. ECOLOGICAL INFORMATION

The product is not classified as dangerous for the environment.
13. DISPOSAL CONSIDERATIONS

Using the information provided in this safety data sheet, advice should be obtained from the relevant environment agency whether the Special Waste Regulations apply.
14. TRANSPORT INFORMATION

Standard bulk handling Recommendations apply, points 7 & 10 are to be followed.
15. REGULATORY INFORMATION

This product is determined as not being dangerous for supply.
The information contained in this safety data sheet does not constitute the user's own assessment of workplace risks as required by other health and safety legislation.
16. OTHER INFORMATION

The product should not be used for purposes other than those shown in Section 1. As the specific conditions of use of the product are outside the suppliers control, the user is responsible for ensuring that the requirements of relevant legislation are complied with.
The information contained within this safety data sheet is based on the present state of knowledge. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of the technical performance or suitability for particular applications.


OCEAN SOLIDS

Garden Enterprises and Information Ltd
102 Armstrong Street
Palmerston North
Phone 06 3570606

MATERIAL SAFETY DATA SHEET: SALT
Section 1: Identification of the Substance
Product name: OCEAN SOLIDS
Recommended use: Gardening
Company details: Details as above
Address: Details as above
Emergency telephone Outside New Zealand: +64 3 35 30199
Number: Within New Zealand: 0800 Chemcall ? (0800 243 62255)
Date of preparation: 26 March 2009

Section 2: Hazards Identification
Inhalation : Very high concentrations of salt dust may result in inflammations of the mucus membranes of the respiratory tract.
Skin Contact : Dry salt and concentrated solutions can cause withdrawal of fluid from the skin and may, on prolonged contact, produce irritation.
Eye Contact : Salt and salt solutions are not toxic to the eye but concentrations much above that of tears cause a stinging sensation.
Ingestion : Acute and chronic toxic effects can result from the ingestion of excessive amounts of either salt or brine. Salt should not be used as an emetic to induce vomiting. High concentrations produce inflammatory reactions in the gastrointestinal tract and can cause vomiting, diarrhea, convulsions and collapse. The ingestion of hypertonic solutions can cause fatal disturbance of body electrolyte and fluid balance particularly in the young and elderly.
Less than a tablespoon of salt may severely poison an infant and sometimes prove fatal.

Issue: C
HSNO Approved MSDS Page 2 March 26, 2009

Section 4: First Aid Measures
Inhalation : Remove patient to fresh air. Keep warm and at rest. Give drinks if desired.
Ingestion : Vomiting will probably occur. Provided the patient is conscious give plenty of liquid to drink. Obtain immediate medical attention especially if vomiting has not occurred.
Eye Contact : Irrigate with eyewash solution or water. If symptoms develop obtain medical help.
Skin Contact : Wash with plenty of water.
Workplace facilities : Emergency showers and eye wash recommended
NOTES FOR MEDICAL PERSONNEL

Swallowed : Give water to drink. No need to induce vomiting.
Eye : Irrigate with copious quantities of slow flowing water for up to 15 minutes. Eyelids to be held open
Skin : Brush off clothing and wash skin thoroughly with plenty of water. Inhaled : Not normally a risk but some may experience some discomfort if working with dusty product. If exposure has occurred allow the victim to drink water.
Section 5: Fire Fighting Measures

Flammability: Non-flammable
Fire fighting agents: Use agents suitable for type of surrounding fire (dry chemical, CO2 water spray or foam).
Special Hazards: Salt withstands temperatures up to its meting point and beyond without decomposing, but at very high temperatures (greater than approximately 800C) a vapor may be emitted which is particularly irritating to the eyes.
Protective Equipment: As applicable to the combustion products associated with the fire.

Section 3: Classification and type
Chemical Name : Sodium Chloride
Synonyms: OCEAN SOLIDS
Chemical Formula: NaCl
CAS Number: 7647-14-5
Issue: C
HSNO Approved MSDS Page 3 March 26, 2009

Section 6: Accidental Release Measures
Personal precautions: Avoid prolonged contact with the skin and inhalation of dust concentrations, otherwise normal good handling and housekeeping practice is adequate. No special protective clothing is required. An eyewash bottle with clean water should be available.
Spillages : Spillages should be swept up or may be safely water hosed to drain under normal circumstances
Section 7: Handling and Storage
Handling : Salt dust is non-flammable but static electricity can be generated by pneumatic conveying, therefore pipes should be bonded and earthed, especially in environments where a spark could prove hazardous.
Storage : Due to its hydroscopic nature, salt should be stored in a dry atmosphere and away from concentrated acids. Absorbs moisture if the relative humidity is above 75 %
Product should be stored in such a way that it does not present a hazard if product were to fall
Issue: C
HSNO Approved MSDS Page 4 March 26, 2009

Section 8: Exposure Controls/Personal Protection
Subsection 1: Workplace Exposure Guidelines
Occupational Exposure : As total dust 10mg/m3 (8hr TWA)
Limits : As respirable dust 4mg/m3 (8hr TWA)
Dangerous Exposure : Non specified.
Engineering Controls : Static electricity can be generated by pneumatic conveying, therefore pipes should be bonded and earthed, especially in environments where a spark could prove hazardous
Subsection 2: Engineering Controls
Respiratory Protection : If the process is such that salt dust is generated, a disposable face mask should be worn.
Hand Protection : Gloves to be worn if prolonged contact is anticipated.
Dry salt and concentrated solutions can cause withdrawal of fluid from the skin.
Eye Protection : Wear chemical safety goggles in situations where contact with the eyes may occur.
Skin Protection : Skin should be washed to remove salt. Dry salt and concentrated solutions can cause withdrawal of fluid from the skin.
Other Protective Measures : An eyewash and hand washing facilities should be readily available.
Section 9: Physical and Chemical Properties
Appearance : Crystalline solid
Colour : White / Colourless
Boiling Point : 1413C
Melting Point : 802C


Wallys 3 in 1for Lawns.

PAGE 1 OF 4 ___________________________________________________________________________ IDENTIFICATION

___________________________________________________________________________ OTHER NAMES:Professor Macs 3 in 1

USE: Soil wetting agent, organic insecticide, Liquid Fertiliser.
UN NUMBER: N/A
HAZCHEM CODE: N/A
DANGEROUS GOODS CLASS: N/A
POISONS SCHEDULE: N/A
PHYSICAL DESCRIPTION/PROPERTIES

APPEARANCE: Dark Brown Liquid
FLASHPOINT (0C): N/A
MELTING POINT (0C): 100C
FLAMMABILITY LIMITS (%): N/A
VAPOUR PRESSURE (___): N/A
SOLUBILITY IN WATER (g/L): 100%
SPECIFIC GRAVITY: 1.01%
INGREDIENTS
CHEMICAL ENTITY
PROPORTION
Ingredients determined not to be hazardous according to Worksafe Criteria 100%
PAGE 2 OF 4

___________________________________________________________________________ Not classified as hazardous according to criteria of Worksafe Australia.

___________________________________________________________________________ HEALTH HAZARD INFORMATION

___________________________________________________________________________ HEALTH EFFECTS
ACUTE:

SWALLOWED: Swallowing large quantities may cause nausea, headaches, irregular heartbeat, cramps and breathing difficulties.
EYES: Irritating to eyes.
SKIN: Non-irritant. Prolonged and repeated contact may cause defatting of skin.
INHALED: Not considered sufficiently volatile to be a problem at ambient temperatures.
FIRST AID

SWALLOWED: Rinse mouth and give plenty of water to drink. Do NOT induce vomiting. If vomiting occurs give further water. Seek medical advice.
EYES: Hold eyes open, immediately flood with water for 15 minutes. Seek medical advice.
SKIN: Wash with soap and water. Contaminated clothing may be re-used following laundering.
INHALED: Recovery is rapid after removal from exposure. If symptoms persist seek medical advice.
FIRST AID FACILITIES: No special first aid facilities are necessary.
ADVICE TO DOCTOR: Treat symptomatically. Contains nitrates. The smooth muscle relaxant effect of nitrate.
Professor Macs Nutri-Gro 3 in 1. M0710 V1

PAGE 3 OF 4
DATE OF ISSUE: 24TH DECEMBER 2007
BARMAC INDUSTRIES PTY LTD
BOX FLAT ESTATE SWANBANK RD. SWANBANK Q 4306
MATERIAL SAFETY DATA SHEET

PRODUCT NAME: BARMAC PROFESSOR MACS NUTRI-GRO 3 IN 1 FOR LAWN AND GARDEN ORGANIC INSECTICIDE, FERTILIZER & WETTING AGENT.
PHONE: (07) 3280 3000
EMERGENCY AFTER HOURS NUMBER: (07) 3280 3000
___________________________________________________________________________ Not classified as hazardous according to criteria of Worksafe Australia.

___________________________________________________________________________ PRECAUTIONS FOR USE

___________________________________________________________________________ EXPOSURE STANDARDS: No exposure limit has been assigned to this product by Worksafe Australia.
ENGINEERING CONTROLS: Maintain adequate ventilation.
PERSONAL PROTECTION:

Skin Protection: Wear loose comfortable clothing. If repeated skin contact is likely, and as good workplace procedure, wear PVC or rubber gloves AS 2161. Wash work clothes regularly.
Eye Protection: Goggles or safety glasses (AS 1336 and AS/NZS 1337) and a face shield should be worn if there is a risk of splash.
Respiratory Protection: If an aerosol or mist is generated, wear a respirator conforming to AS/NZS 1715 and 1716.
FLAMMABILITY: Non Flammable. May emit toxic fumes if heated to decomposition. SCBA should be used in a fire situation.
Professor Macs Nutri-Gro 3 in 1. M0710 V1

PAGE 4 OF 4
DATE OF ISSUE: 24TH DECEMBER 2007
BARMAC INDUSTRIES PTY LTD
BOX FLAT ESTATE SWANBANK RD. SWANBANK Q 4306
MATERIAL SAFETY DATA SHEET
PRODUCT NAME: BARMAC PROFESSOR MACS NUTRI-GRO 3 IN 1 FOR LAWN AND GARDEN ORGANIC INSECTICIDE, FERTILIZER & WETTING AGENT.
PHONE: (07) 3280 3000
EMERGENCY AFTER HOURS NUMBER: (07) 3280 3000

___________________________________________________________________________ Not classified as hazardous according to criteria of Worksafe Australia.
___________________________________________________________________________ ________________________________________________________________________ SAFE HANDLING INFORMATION

___________________________________________________________________________ STORAGE AND TRANSPORT: Not classified as a Dangerous Good under the ADG Code. Store in a cool dry place.
SPILLS AND DISPOSAL: Take precautions against slippery surfaces during any spills. Wash down with water but avoid this product getting into drains, sewers and waterways. Bund and pump into suitable drum for re-use. Dispose of in compliance with State Land Management Authority requirements.
FIRE/EXPLOSION HAZARD: Not Flammable. For fires involving this material, use any means suitable for extinguishing surrounding fire. Decomposition may give rise to toxic and noxious fumes. Wear self-contained breathing apparatus (SCBA).

________________________________________________________________________________ NOTICE: Information for this product is believed to be reliable, however buyer and user assume all risk of use, handling and storage whether in accordance with directions or not. Barmac Industries Pty Ltd and its agents give no guarantee or warranty of any kind express or implied concerning the use of this product and will not accept any responsibility whatsoever whether in contract or tort for any loss including consequential loss arising out of the use of this product or caused by this product.
Wallys 3 in 1 for Lawns. M0710 V1


MATERIAL SAFETY DATA SHEET
SODIUM BICARBONATE SDC 685

STATEMENT OF HAZARDOUS NATURE: This material is not classified as a Hazardous material according to the criteria of NZS 5433:1999 "Transport of Dangerous Goods on Land" This material is not a scheduled poison according to the criteria of the Toxic Substances Regulations 1983.
IDENTIFICATION
Product Name: Sodium Bicarbonate
Other Name: Sodium Hydrogen Carbonate, Baking Soda, Bicarbonate of Soda.
Manufacturer's Product Code: Not applicable
U.N. Number: None Allocated
Dangerous Goods Class: None Allocated
Packaging Group: None Allocated
Hazchem Code: None Allocated
Toxic Substances Schedule: Not listed
Physical Description/Properties
Appearance: Fine white powder
Boiling Point/Melting Point: Decomposes 270oC
Vapour Pressure: Not available
Specific Gravity: 2.160
Flash Point: Not available
Flammability Limits: Not available
Solubility in Water: Soluble
Other Properties:
Ingredients Chemical Entity ; CAS No ; Proportion
Sodium Bicarbonate ; 144-55-8 ; 100%.
HEALTH HAZARD INFORMATION
Health Effects
Acute:
Swallowed: Ingestion of large amounts may cause nausea and irritation of stomach.
Eye: Can cause irritation of soft tissue.
Skin: Repeated or prolonged skin contact can lead to mild irritation particularly if skin is moist.
Inhaled: Inhalation of dust may result in respiratory irritation.
Chronic:
First Aid
Swallowed: Do NOT induce vomiting. Rinse mouth with milk or water. Give large amounts of water or milk to drink to achieve dilution. If vomiting occurs give further milk or water. Seek urgent medical assistance.
Eye: Flush affected eye(s) with copious amounts of cold or luke warm water for at least 15 minutes retracting eyelids frequently. Seek medical assistance.
Skin: Flood affected area with copious amounts of soap and water, remove contaminated clothing and launder before reuse. If rash or discolouration appears or persists seek medical assistance.
Inhaled: Remove to fresh air, loosen restrictive clothing. Blow nose thoroughly and swab nasal passages with damp cotton wool. Allow to rest and keep warm. If recovery is not rapid and complete seek medical assistance.
Advice to Doctor: Treat symptomatically. Refer to National Poisons and Hazardous Chemicals Information Centre.
PRECAUTIONS FOR USE
Exposure Standards: Not listed. NZ WES-TWA : Nuisance Dust 10mg/m3
Engineering Controls: Use in well ventilated area. Use protective breathing apparatus as required.
Personal Protection: Wear overalls, rubber gloves and goggles when handling. Wear repirator if local exhaust ventilation inadequate.
Flammability: Non flammable. Decomposes when subjected to extreme heat.
SAFE HANDLING INFORMATION
Storage and Transport: Transport and store in dry cool conditions. Do not store near acids.
Spills and Disposal: Wear protective equipment. Sweep up but avoid generating dust. Prevent contamination of drains and waterways. Collect and seal in containers for disposal in accordance with local authority regulations
Fire/Explosion Hazard: Normally stable. Decomposes to give carbon dioxide and monoxide. Reacts vigorously with acids to liberate carbon dioxide gas.
OTHER INFORMATION

CONTACT POINT
Clark Products Ltd, 24-28 Niven Street Napier
Business Hours 8am to 5pm Monday to Friday
Phone : (06) 843 6049 Fax (06) 843 2758
24 HOUR EMERGENCY HELP
Phone : 0800CHEMCALL (0800 243 622)
National Poisons and Hazardous Chemicals Information Centre
Phone (03) 474 7000
This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all current legislation.

Top Of Page


MATERIAL SAFETY DATA SHEET Boric Acid SDC105

STATEMENT OF HAZARDOUS NATURE: This material is not classified as a Hazardous material according to the criteria of NZS:5433.1999 "Transport of Dangerous Goods on Land". This material is a scheduled poison according to the criteria of the Toxic Substances Regulations 1983.
IDENTIFICATION
Product Name: Boric Acid
Shipping Name: Not Applicable
Manufacturer's Product Code: Not Applicable
U.N. Number: Not Applicable
Dangerous Goods Class: Not Applicable
Packaging Group: Not Applicable
Hazchem Code: Not Applicable
Toxic Substances Schedule: 4
Physical Description/Properties
Appearance: White powder or granules
Boiling Point/Melting Point: MP: 171oC
Vapour Pressure: Not available
Specific Gravity: 1.4 @ 20oC
Flash Point: Not Applicable
Flammability Limits: Not Applicable
Solubility in Water: 4.6% by weight @ 20oC
Other Properties:
Ingredients
Chemical Entity CAS No Proportion
Boric Acid 10043-35-3 99%
Ash to 100%
HEALTH HAZARD INFORMATION
Health Effects

Acute
Swallowed: Abdominal pain, vomiting and diarrhoea
Eye: Irritant
Skin: Mild irritation, harmful if absorbed through broken skin.
Inhaled: Harmful. Irritant to soft tissue.
Chronic Kidney, liver diseases may be aggrevated by exposure to this material.
First Aid
Swallowed: Rinse mouth with milk or water. Induce vomiting by either administering an emetic syrup or putting fingers down throat. Seek urgent medical assistance.
Eye: Flush affected eye(s) with copious amounts of cold or luke warm water for at least 15 minutes retracting eyelids frequently. Seek medical assistance.
Skin: Flood affected area with copious amounts of soap and water, remove contaminated clothing and launder before reuse. If rash or discolouration appears or persists seek medical assistance.
Inhaled: Remove to fresh air, or remove source of contamination. Loosen restrictive clothing. If breathing has stopped apply artificial respiration or CPR immediately. Seek urgent medical assistance
Advice to Doctor: Treat symptomatically. Refer to National Poisons and Hazardous Chemicals Information Centre.
PRECAUTIONS FOR USE
Exposure Standards: NZ WES-TWA: 5mg/m3
Engineering Controls: Avoid generating and inhaling dust. Use with local exhaust ventilation and while wearing respiration. Keep containers closed when not in use.
Personal Protection: Wear overalls, rubber gloves, goggles and dust mask when handling.
Flammability: Non-combustible
SAFE HANDLING INFORMATION
Storage and Transport: Keep dry; avoid excessive heat.
Spills and Disposal: Wear protective equipment. Sweep up but avoid generating dust. Prevent contamination of drains and waterways. Collect and seal in containers for disposal in accordance with local authority regulations
Fire/Explosion Hazard: Non flammable. Stable at ambient temperatures. Does not support combustion. Use firefighting media suitable for surrounding fire.
OTHER INFORMATION

CONTACT POINT
Clark Products Ltd, 24-28 Niven Street Napier
Business Hours 8am to 5pm Monday to Friday
Phone : (06) 843 6049 Fax (06) 843 2758
24 HOUR EMERGENCY HELP
Phone : 0800CHEMCALL (0800 243 622)
National Poisons and Hazardous Chemicals Information Centre
Phone (03) 474 7000
This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all current legislation.

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MATERIAL SAFETY DATA SHEET COPPER SULPHATE SDC205

STATEMENT OF HAZARDOUS NATURE: This material is not classified as a Hazardous material according to the criteria of NZS 5433:1999 "Transport of Dangerous Goods on Land". This material is not a scheduled poison according to the criteria of the Toxic Substances Regulations 1983.
IDENTIFICATION
Product Name: Copper Sulphate
Other Name: Blue Stone, Blue Vitriol, Cupric Sulphate
Manufacturer's Product Code: Not Applicable
U.N. Number: None Allocated
Dangerous Goods Class: None Allocated
Packaging Group: None Allocated
Hazchem Code: None Allocated
Toxic Substances Schedule: Not Listed
Physical Description/Properties
Appearance: Blue crystals or crystalline granules
Boiling Point/Melting Point: Not available
Vapour Pressure: Not available
Specific Gravity: 2.284
Flash Point: Not available
Flammability Limits: Not available
Solubility in Water: Soluble
Other Properties: Ingredients
Chemical Entity CAS No Proportion
Copper sulphate pentahydrate 7758-99-8 >98%
Inerts - to 100%
HEALTH HAZARD INFORMATION
Health Effects
Acute
Swallowed: Acute poisoning shows symptoms of vomiting, gastric pain, dizziness, convulsions, shock, coma and possibly death. As little as 10grams of Copper Sulphate ingestion has been reported as causing death, although victims have recovered after taking far larger doses. Copper salts tend to cause vomiting and for this reason, poisoning by ingestion of large amounts is rare.
Eye: Irritant to mucous tissue.
Skin: Chronic exposure may cause irritation & dermititus
Inhaled: Irritant to mucous tissue.
Chronic Poisoning by ingestion may give rise to kidney damage, enlargement of liver and jaundice.
First Aid
Swallowed: Rinse mouth with milk or water. Induce vomiting by either administering an emetic syrup or putting fingers down throat. Seek urgent medical assistance.
Eye: Flush affected eye(s) with copious amounts of cold or luke warm water for at least 15 minutes retracting eyelids frequently. Seek medical assistance.
Skin: Flood affected area with copious amounts of soap and water, remove contaminated clothing and launder before reuse. If rash or discolouration appears or persists seek medical assistance.
Inhaled: Remove to fresh air, loosen restrictive clothing. Blow nose thoroughly and swab nasal passages with damp cotton wool. Allow to rest and keep warm. If recovery is not rapid and complete seek medical assistance.
Advice to Doctor: Treat symptomatically. Refer to National Poisons and Hazardous Chemicals Information Centre.
PRECAUTIONS FOR USE
Exposure Standards: NZ WES-TWA Copper dusts 1mg/m3 (as copper)
Engineering Controls: Natural ventilation should be adequate under normal use conditions. Avoid generating and inhaling dust.
Personal Protection: Wear overalls, rubber gloves, goggles and dust mask when handling.
Flammability: The material is non-flammable.
SAFE HANDLING INFORMATION
Storage and Transport: Store in cool dry place.
Spills and Disposal: Wear protective equipment. Sweep up but avoid generating dust. Prevent contamination of drains and waterways. Collect and seal in containers for disposal in accordance with local authority regulations
Fire/Explosion Hazard: Non flammable. Stable at ambient temperatures. Does not support combustion. Use firefighting media suitable for surrounding fire.
OTHER INFORMATION
CONTACT POINT

Clark Products Ltd, 24-28 Niven Street Napier
Business Hours 8am to 5pm Monday to Friday
Phone : (06) 843 6049 Fax (06) 843 2758
24 HOUR EMERGENCY HELP
Phone : 0800CHEMCALL (0800 243 622)
National Poisons and Hazardous Chemicals Information Centre
Phone (03) 474 7000
This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all current legislation.
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MATERIAL SAFETY DATA SHEET DIATOMACEOUS EARTH SDC245

STATEMENT OF HAZARDOUS NATURE: This material is not classified as a Hazardous material according to the criteria of NZS5433:1999 "Transport of Dangerous Goods on Land". This material is not a scheduled poison according to the criteria of the Toxic Substances Regulations 1983.
IDENTIFICATION
Product Name: Diatomaceous Earth
Other Name: Filter powder, Diatomite, Dicalite, Celatom
Manufacturer's Product Code: Not Applicable
U.N. Number: None Allocated
Dangerous Goods Class: None Allocated
Packaging Group: None Allocated
Hazchem Code: None Allocated
Toxic Substances Schedule: Not Listed
Physical Description/Properties
Appearance: White to off-white powder, odourless
Boiling Point/Melting Point: Sintering point : 1593oC
Vapour Pressure: Not available
Specific Gravity: 2.3
Flash Point: Not applicable
Flammability Limits: Not applicable
Solubility in Water: Slight
Other Properties:
Ingredients
Chemical Entity CAS No Proportion
Fluxcalcined Diatomaceous Earth 68855-54-9 100%
HEALTH HAZARD INFORMATION
Health Effects
Acute
Swallowed: Low Toxicity
Eye: Dust may cause severe irritation.
Skin: Non-irritant
Inhaled: Dust may cause irritation, may aggravate asthma, bronchitis, emphysema.
Chronic Long term exposure to silica dusts may cause pnenmonconiosis and silicosis.
First Aid
Swallowed: Seek medical advice
Eye: Flush affected eye(s) with copious amounts of cold or luke warm water for at least 15 minutes retracting eyelids frequently. Seek medical assistance.
Skin: Flood affected area with copious amounts of soap and water, remove contaminated clothing and launder before reuse. If rash or discolouration appears or persists seek medical assistance.
Inhaled: Remove to fresh air, loosen restrictive clothing and allow to rest. Keep warm. If recovery is not rapid and complete seek medical assistance.
Advice to Doctor: Persons with impaired lung function or asthma, may suffer increased difficulty breathing, after inhalation of this dust.
PRECAUTIONS FOR USE
Exposure Standards: NZ WES TWA:Amorphous silica 10mg/m3
Engineering Controls: Use in well ventilated area. Use protective breathing apparatus as required.
Personal Protection: Wear overalls, rubber gloves, goggles and dust mask when handling.
Flammability: Non flammable
SAFE HANDLING INFORMATION
Storage and Transport: Store in cool, dry place, avoid damaging bags while in transit or storage. Incompatible with Hyphafluoric acid.
Spills and Disposal: Wear protective equipment. Sweep up but avoid generating dust. Prevent contamination of drains and waterways. Collect and seal in containers for disposal in accordance with local authority regulations.
Fire/Explosion Hazard: Will not burn. Containers exposed to fire may be cooled with water.
OTHER INFORMATION
CONTACT POINT

Clark Products Ltd, 24-28 Niven Street Napier
Business Hours 8am to 5pm Monday to Friday
Phone : (06) 843 6049 Fax (06) 843 2758
24 HOUR EMERGENCY HELP
Phone : 0800CHEMCALL (0800 243 622)
National Poisons and Hazardous Chemicals Information Centre
Phone (03) 474 7000
This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all current legislation.

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PRODUCT
Trade Name Wallys LIME SULPHUR
Product Dormant season fungicide, insecticide, miticide
Formulation type Soluble Concentrate
Ingredients 1. Calcium Polysulphide
2. Water
Active ingredient(s) Sulphur as Polysulphide of calcium
Fungicidal and Dessicant action via alkalinity. oxidises to elemental sulphur
PHYSICAL
Specific Gravity 1000g per litre
Solubility in Water Readily Soluble
Flammability Non-Flammable.
HAZARD IDENTIFICATION
Inhalation AVOID INHALING FUMES, OR SPRAY MIST. SULPHIDE FUMES MAY RESULT IN RESPIRATORY UPSET.
Eye irritation AVOID CONTACT WITH EYES. PRODUCT IS CORROSIVE AND ALKALINE,
Skin Absorption AVOID CONTACT WITH SKIN. PRODUCT IS IRRITANT
Ingestion CAN CAUSE SERIOUS INTERNAL DAMAGE IF SWALLOWED
Chronic NONE
Re-entry When Dry
TOXICOLOGY
MODERATE TOXICITY
ORAL LD50 -
DERMAL LD50 -
INHALATION -
ECOTOXICITY -.
FIRST AID MEASURES
Inhalation Remove patient to fresh air. If respiratory symptoms arise consult physician.
Eye Contact Wash eyes with plenty of warm water for approximately 15 minutes. Seek medical assistance.
Skin Contact Remove clothing from affected area, and wash with warmwater and detergent. If allergic reaction arises consult physician.
Ingestion Give plenty of water.
Emergency Treatment No recommended procedures.
ACCIDENTAL SPILLAGE
Land Spill Absorb and dispose of spilt material, then flush area with water. Ventilate area.
Contamination of waterway Avoid further spillage of concentrate into waterway. Ensure adequate dilution of spilt material.
HANDLING AND STORAGE
Storage Store Sealed , dry under cool dark conditions
Exposure and Personal Protection
Applicators Protective clothing - EYE SKIN RESPIRATOR required for application.
Re-Packaging of Product Skin Protection (gloves), Respiratory and eye protection required.
Re pack product in a well ventilated area.

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MATERIAL SAFETY DATA SHEET
MAGNESIUM SULPHATE SDC420

STATEMENT OF HAZARDOUS NATURE: This material is not classified as a Hazardous material according to the criteria of NZS5433:1999 "Transport of Dangerous Goods on Land" This material is not a scheduled poison according to the criteria of the Toxic Substances Regulations 1983.
IDENTIFICATION
Product Name: Magnesium Sulphate
Other Name: Epsom Salts
Manufacturer's Product Code: Not Applicable
U.N. Number: None Allocated
Dangerous Goods Class: None Allocated
Packaging Group: None Allocated
Hazchem Code: None Allocated
Toxic Substances Schedule: Not Listed
Physical Description/Properties
Appearance: White, fine, odouless colorless crystals
Boiling Point/Melting Point: Decomposes @ 1124oC
Vapour Pressure: Not Available
Specific Gravity: Not Available
Flash Point: Not Available
Flammability Limits: Not Available
Solubility in Water: Very Soluble
Other Properties: Soluble in Glycerol
Ingredients
Chemical Entity CAS No Proportion
Magnesium Sulfate 7587-88-9 100%
HEALTH HAZARD INFORMATION
Health Effects
Acute
Swallowed: Ingestion of large amounts may cause thirst, flushing of skin, and respiratory dysfunction.
Eye: Can cause irritation to mucous and tissue.
Skin: Can cause irritation of sensitive skin.
Inhaled: Inhalation of solid material can cause nasal and respiratory tract irritation.
Chronic No data available
First Aid
Swallowed: Do NOT induce vomiting. Rinse mouth with milk or water. Give large amounts of water or milk to drink to achieve dilution. If vomiting occurs give further milk or water. Seek urgent medical assistance.
Eye: Flush affected eye(s) with copious amounts of cold or luke warm water for at least 15 minutes retracting eyelids frequently. Seek medical assistance.
Skin: Flood affected area with copious amounts of soap and water, remove contaminated clothing and launder before reuse. If rash or discolouration appears or persists seek medical assistance.
Inhaled: Remove to fresh air, loosen restrictive clothing. Blow nose thoroughly and swab nasal passages with damp cotton wool. Allow to rest and keep warm. If recovery is not rapid and complete seek medical assistance
Advice to Doctor: Magnesium Salts are generally of low toxicity and are normally rapidly excreted from the body. Systemic poisoning can occur where there is a history of impaired renal function. Treat as appropriate to symptoms evident.
PRECAUTIONS FOR USE
Exposure Standards: Not listed. NZ WES-TWA: Nuisance Dust 10 mg/m3
Engineering Controls: Natural ventilation should be adequate under normal use conditions. Avoid generating and inhaling dust.
Personal Protection: Wear overalls, rubber gloves, goggles and dust mask when handling.
Flammability: Non-Flammable - will not support combustion.
SAFE HANDLING INFORMATION
Storage and Transport: Keep dry and cool
Spills and Disposal: Wear protective equipment. Sweep up but avoid generating dust. Prevent contamination of drains and waterways. Collect and seal in containers for disposal in accordance with local authority regulations.
Fire/Explosion Hazard: Non flammable. Stable at ambient temperatures. Does not support combustion. Use fire fighting media suitable for surrounding fire.
OTHER INFORMATION
CONTACT POINT
Clark Products Ltd, 24-28 Niven Street Napier
Business Hours 8am to 5pm Monday to Friday
Phone : (06) 843 6049 Fax (06) 843 2758
24 HOUR EMERGENCY HELP
Phone : 0800CHEMCALL (0800 243 622)

National Poisons and Hazardous Chemicals Information Centre
Phone (03) 474 7000
This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all current legislation.

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PRODUCT

Trade Name Matrix Reloaded
Product HORTICULTURAL FERTILIZER
Manufacturer Otaki Hydroponics ltd.
Formulation type Suspension Concentrate
Ingredients: Calcium Nitrate, MonoPotassium Phosphate, Potassium Nitrate, magnesium Sulphate, Iron EDTA, Manganese Sulfate, Boric Acid, Zinc Sulfate, Copper Sulfate, Ammonium Molybdate, Nickel Sulfate, Cobalt Sulfate, Potassium Iodide, Potassium Dichromate, Sodium Selenate, Acozine blue or Rubinol red, Synthetic stabilising agent (gum).
Active ingredient(s) Mineral ions
PHYSICAL
Specific Gravity 1000 g per litre
Solubility in Water Soluble.
Flammability Non-Flammable. Non Explosive.
HAZARD IDENTIFICATION
Inhalation NONE
Eye irritation MILDLY ACIDIC, HIGHLY SALINE as CONCENTRATE.
Skin Absorption NONE- ALTHOUGH CAN HAVE IRRITANT EFFECT ON EXPOSED SKIN
Ingestion NONE
CHRONIC Long Term exposure to nitrates and some trace elements can be damaging to health.
TOXICOLOGY
ORAL LD50 - (NON TOXIC)
DERMAL LD50 -
Ecotoxicity May cause algal bloom. Can be toxic to fish.
FIRST AID MEASURES
Inhalation NONE REQUIRED.
Eye Contact Wash eyes with plenty of warm water for approximately 15 minutes. Seek medical assistance if allergic reaction occurs.
Skin Contact Remove clothing from affected area, and wash with warmwater and detergent. If allergic reaction arises consult physician.
Ingestion No recommended procedures.
Emergency Treatment No recommended procedures.
ACCIDENTAL SPILLAGE
Land Spill Absorb and dispose of spilt material. Flush area with hot water to reduce residue.
Contamination of waterway Avoid further spillage of concentrate into waterway. Ensure adequate dilution of spilt material.
HANDLING AND STORAGE
Storage Store dry under cool dark conditions
EXPOSURE AND PERSONAL PROTECTION
Applicators Minimal Protective clothing required for application.
Re-Packaging of Product Skin Protection (gloves) recommended.

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MATERIAL SAFETY DATA SHEET
SDC485 - Nansa HS 80AU

STATEMENT OF HAZARDOUS NATURE: This material is not classified as a Hazardous material according to the criteria of NZS5433:1999 "Transport of Dangerous Goods on Land" This material is not a scheduled poison according to the criteria of the Toxic Substances Regulations 1983.
IDENTIFICATION
Product Name: Nansa HS 80AU
Other Name: Sodium Alkylbenzene Sulphonate, sodium dodecylbenzene sulphonate
Manufacturer's Product Code: Not Applicable
U.N. Number: None Allocated
Dangerous Goods Class: None Allocated
Packaging Group: None Allocated
Hazchem Code: None Allocated
Toxic Substances Schedule: Not listed
Physical Description/Properties
Appearance: White to cream coloured free flowing powder.
Boiling Point/Melting Point: Not available
Vapour Pressure: Not available
Specific Gravity: Packing Density: 0.55
Flash Point: Not available
Flammability Limits: Not available
Solubility in Water: approx 150g/l (20 degrees celcius)
Other Properties:
Ingredients
Chemical Entity CAS No Proportion
Sodium Alkylbenzene sulphate 68081-81-2 80%
Sodium Sulphate 7757-82-6 14%
Non Hazardous inerts ----------- to 100%
HEALTH HAZARD INFORMATION
Health Effects
Acute
Swallowed: Moderate irritant
Eye: Dust is eye irritant
Skin: Prolonged or repeated contact may produce dermatitis
Inhaled: Dust is irritating to nose, throat and lungs.
Chronic No data available
First Aid
Swallowed: Do NOT induce vomiting. Rinse mouth with milk or water. Give large amounts of water or milk to drink to achieve dilution. If vomiting occurs give further milk or water. Seek urgent medical assistance.
Eye: Flush affected eye(s) with copious amounts of cold or luke warm water for at least 15 minutes retracting eyelids frequently. Seek medical assistance.
Skin: Flood affected area with copious amounts of soap and water, remove contaminated clothing and launder before reuse. If rash or discolouration appears or persists seek medical assistance.
Inhaled: Remove to fresh air, loosen restrictive clothing. Blow nose thoroughly and swab nasal passages with damp cotton wool. Allow to rest and keep warm. If recovery is not rapid and complete seek medical assistance
Advice to Doctor: Treat symptomatically. Refer to National poisons and Hazardous Chemicals Information Centre.
PRECAUTIONS FOR USE
Exposure Standards: Not listed. NZ WES-TWA: Nuisance Dust 10 mg/m3
Engineering Controls: Use in well ventilated area. Use protective breathing apparatus as required.
Personal Protection: Wear overalls, rubber gloves and goggles when handling. Wear repirator if local exhaust ventilation inadequate.
Flammability: Not flammable. Does not support combustion.
SAFE HANDLING INFORMATION
Storage and Transport: Store in a dry place away from foodstuffs and oxidising agents. Bags should be protected from damage and mild stell drums should not be used for prolonged storage of solutions of these products. Keep containers tightly closed when not in use to prevent moisture absorbtion and craking.
Spills and Disposal: Wear protective equipment. Sweep up but avoid generating dust. Prevent contamination of drains and waterways. Collect and seal in containers for disposal in accordance with local authority regulations.
Fire/Explosion Hazard: Not flammable but in a large fire may evolve toxic fumes containing sulphur dioxide and carbon monoxide.
OTHER INFORMATION
CONTACT POINT
Clark Products Ltd, 24-28 Niven Street Napier
Business Hours 8am to 5pm Monday to Friday
Phone : (06) 843 6049 Fax (06) 843 2758
24 HOUR EMERGENCY HELP
Phone : 0800CHEMCALL (0800 243 622)
National Poisons and Hazardous Chemicals Information Centre
Phone (03) 474 7000
This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all current legislation.
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MATERIAL SAFETY DATA SHEET Cold Pressed Wallys Neem Tree Oil TM

NOTE NOW A DISCONTINUED PRODUCT: 11/9/2017

1.

IDENTIFICATION

Product Name. . . . . . . . . . . . . . . . . . . . . . . . . . . . Wallys Neem Tree Oil
Chemical Name. . . . . . . . . . . . . . . . . . . . . . . . . . . Neem oil.
Other Name/s. . . . . . . . . . . . . . . . . . . . . . . . . . . . . Not applicable.
Distributor/packaged by Name. . . . . . . . . . . . . . . . . . . . . . . Garden Enterprises & Information Ltd.
Telephone Number. . . . . . . . . . . . . . . . . . . . . . . . . 06 3570606.
U.N. Number. . . . . . . . . . . . . . . . . . . . . . . . . . . . . None allocated.
Dangerous Goods Class. . . . . . . . . . . . . . . . . . . . None allocated.
Secondary Risk. . . . . . . . . . . . . . . . . . . . . . . . . . . None allocated.
Hazchem Group. .'. . . . . . . . . . . . . . . . . . . . . . . . . None allocated.
Pack Group. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . None allocated.
EPG . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . None allocated.
Poisons Schedule. . . . . . . . . . . . . . . . . . . . . . . . . S6.
1. Physical Description/Properties

Appearance. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Brown liquid.
Odour. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Slight smell.
pH. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 - 7
Flammability. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Not flammable.
Solubility in Water. . . . . . . . . . . . . . . . . . . . . . . . . . Fully miscible in water.
Lower Explosion Limit. . . . . . . . . . . . . . . . . . . . . . Not data available.
Upper Explosion Limit. . . . . . . . . . . . . . . . . . . . . . No data available.
Vapour Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.46 (air = 1).
Specific Gravity. . . . . . . . . . . . . . . . . . . . . . . . . . .0.840 gm/ml.
Melting Point. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80C
Boiling Point. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 240C
Vapour Pressure. . . . . . . . . . . . . . . . . . . . . . . . . . .38 at 20C
Evaporation Rate. . . . . . . . . . . . . . . . . . . . . . . . . . No data available.
Reactivity Data. . . . . . . . . . . . . . . . . . . . . . . . . . . . Incompatible with oxidising agents, reducing materials, alkai metals and acids. Possible hazardous decomposition at higher temperature may cause irritative fumes.

1.1 Other Properties. . . . . . . . . . . . . . . . . . . . . . Photosensitive. Degradable under UV conditions.
1.2 Ingredients.... . . . . . . . . . . . . . . . . . . . . . . . . Azadirachta indica seed oil, Tergitol NP9 emulsifier.
2 HEALTH HAZARD INFORMATION

2.1 Health Effects

General. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . No data available.
Ingestion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . No data available.
Eye Contact. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . No data available.
Skin Contact. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . No data available.
Inhalation. . . . . . , . . . . . . . . . . . . . . . . . . . . . . . . . No data available.
2.2 First Aid and Emergency Procedures

Ingestion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Immediately flush with plenty of water.
Eye Contact. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Remove contaminated clothing.
Skin Contact. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Remove to fresh air. Consult a physician.
Inhalation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . No data available.
2.3 First Aid Facilities. . . . . . . . . . . . . . . . . . . . . For advice contact a poisons information centre (Phone New Zealand 0800 764 766) or a doctor at once.
2.4 Toxicity Data. . . . . . . . . . . . . . . . . . . . . . . . . . Oral (rat) >5000 mg/kg, Inhalation >2.11 :f:0.06mgll air, Eye - no irritant, Human Ingestion - no data available.
3 PRECAUTIONS FOR USE 3.1 Conditions to Avoid. . . . . . . . . . . . . . . . . . . Avoid prolonged exposure to sunlight.
3.2 Personal Protection. . . . . . . . . . . . . . . . . . . Normal industrial clothing and ventilation recommended.
3.3 Special Fire Fighting Procedures. . . . . None.
3.4 Flammability. . . . . . . . . . . . . . . . . . . . . . . . . . Non combustible.
4 SAFE HANDLING INFORMATION

4.1 StoragelTransport..................... No special storage and transport requirements.
This product has no UN classification. This product is a S6 Poison. Observe all relevant regulations regarding sale, transport and storage of this class of product. Containers should be kept closed in order to minimise contamination. Keep from extreme heat and open flames, and make sure that the product does not come into contact with substances listed under "Reactivity Data" above.

4.2 Packaging/Labelling
UN No . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Not applicable.
Pack Group. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Not applicable.
Class. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Not applicable.
Hazchem Code. . . . . . . . . . . . . . . . . . . . . . . . . . . Not applicable.
Subs Risk. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Not applicable.
EPG No . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Not applicable.
Shipping Name. . . . . . . . . . . . . . . . . . . . . . . . . . . . Crop oil - wetter/sticker.
Hazard. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Not applicable.
4.3 Spills and Disposal

Spilled Material. . . . . . . . . . . . . . . . . . . . . . . . . . . . Land: ventilate area of spill and clean up. Water: flush with clean water.
Disposal. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . In accordance with local and national regulations.
4.4 Fire/Explosion Hazard Fire/Explosion. . . . . . . . . . . . . . . . . . . . . . . . . . . . None.
Extinguishing Media. . . . . . . . . . . . . . . . . . . . . . . . Material is non-combustible, however, as product is oil-based, use C020r polymer foam.
5 OTHER INFORMATION. . . . . . . . . . . . . . No data available.
DISCLAIMER
The data and recommendations presented herein are based upon research of others and are believed to be accurate. However, no warranty is expressed or implied regarding this data or the results to be obtained from use thereof. Garden Enterprises and Information Ltd, assumes no responsibility for the injury to customers or third party proximity caused by the material if reasonable safety procedures are not adhered to as stipulated in this data sheet. .


MATERIAL SAFETY DATA SHEET Wallys Neem Tree Granules TM & Wallys Neem Tree Powder TM

1.

IDENTIFICATION

Products Name. . . . . . . . . . . . . . . . . . . . . . . . . . . . Wallys Neem Tree Granules TM & Wallys Neem Tree Powder TM
Chemical Name. . . . . . . . . . . . . . . . . . . . . . . . . . . None allocated.
Other Name/s. . . . . . . . . . . . . . . . . . . . . . . . . . . . . Neem Cake-Organic Fertiliser.
Distributor/Packaged by Name. . . . . . . . . . . . . . . . . . . . . . .Garden Enterprises and Information Ltd.
Telephone Number. . . . . . . . . . . . . . . . . . . . . . . . . 06 3570606
U.N. Number. . . . . . . . . . . . . . . . . . . . . . . . . . . . . None allocated.
Dangerous Goods Class. . . . . . . . . . . . . . . . . . . . None allocated.
Secondary Risk. . . . . . . . . . . . . . . . . . . . . . . . . . . None allocated.
Hazchem Group. . . . . . . . . . . . . . . . . . . . . . . . . . . None allocated.
Pack Group. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . None allocated.
EPG . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . None allocated.
Poisons Schedule. . . . . . . . . . . . . . . . . . . . . . . . . S6
1.1 Physical Description/Properties Appearance. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Dark brown granules interspersed with light brown fibrous particles.
Odour. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Slight organic odour.
pH. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6 - 7
Flammability. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Not flammable.
Solubility in Water. . . . . . . . . . . . . . . . . . . . . . . . . . Not miscible in water.
Lower Explosion Limit. . . . . . . . . . . . . . . . . . . . . . Not data available.
Upper Explosion Limit. . . . . . . . . . . . . . . . . . . . . . No data available.
Vapour Density. . . . . . . . . . . . . . . . . . . . . . . . . . . . No data available.
Specific Gravity. . . . . . . . . . . . . . . . . . . . . . . . . . . No data available.
Melting Point. . . . . . . . . . . . . . . . . . . . . . . . . . . . . No data available.
Boiling Point. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . No data available.
Vapour Pressure. . . . . . . . . . . . . . . . . . . . . . . . . . . No data available.
Evaporation Rate. . . . . . . . . . . . . . . . . . . . . . . . . . No data available.
Reactivity Data. . . . . . . . . . . . . . . . . . . . . . . . . . . . No data available.
1.2 Other Properties. . . . . . . . . . . . . . . . . . . . . . Photosensitive. Degradable under UV conditions.
1.3 Ingredients. . . . . . . . . . . . . . . . . . . . . . . . . . . . Azadirachta indica seed husks.
Neem cake has an adequate quantity of NPK in organic form for plant growth.
Being a totally botanical product it contains 100% natural NPK content and other essential micro nutrients as N(Nitrogen 2.0% to 5.0%), P(Phosphorus 0.5% to 1.0%), K(Potassium 1.0% to 2.0%), Ca(Calcium 0.5% to 3.0%), Mg(Magnesium 0.3% to 1.0%), S(Sulphur 0.2% to 3.0%), Zn(Zinc 15 ppm to 60 ppm), Cu(Copper 4 ppm to 20 ppm), Fe (Iron 500 ppm to 1200 ppm), Mn (Manganese 20 ppm to 60 ppm).
It is rich in both sulphur compounds and bitter limonoids.
According to research calculations, neem cake seems to make soil more fertile due to an ingredient that blocks soil bacteria from converting nitrogenous compounds into nitrogen gas.
It is a nitrification inhibitor and prolongs the availability of nitrogen to both short duration and long duration crops.
Neem seed cake also reduce alkalinity in soil, as it produces organic acids on decomposition.
Being totally natural, it is compatible with soil microbes and rhizosphere microflora and hence ensures fertility of the soil.
Neem cake improves the organic matter content of the soil, helping improve soil texture, water holding capacity, and soil aeration for better root development.

2 HEALTH HAZARD INFORMATION

2.1 Health Effects

General..................................................................No Data Available
Ingestion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Non Toxic.
Eye Contact. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Non irritant.
Skin Contact. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . No .data available.
Inhalation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . No data available.
2.2 First Aid and Emergency Procedures

Ingestion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Non -Toxic.
Eye Contact. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Flush eyes with plenty of water.
Skin Contact. . . . .'. . . . . . . . . . . . . . . . . . . . . . . . . Remove contaminated clothes and wash skin with plenty of water.
Inhalation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . No data available.
2.3 First Aid Facilities. . . . . . . . . . . . . . . . . . . . . For advice contact a poisons information center (Phone New Zealand 0800 764 766) or a doctor at once.
2.4 Toxicity Data. . . . . . . . . . . . . . . . . . . . . . . . . . Oral (rat) >11000 mg/kg, Eye - no irritant,
Human Ingestion - no data available.
3 PRECAUTIONS FOR USE 3.1 Conditions to Avoid. . . . . . . . . . . . . . . . . . . Avoid prolonged exposure to sunlight.
3.2 Personal Protection. . . . . . . . . . . . . . . . . . . Normal industrial clothing and ventilation recommended.
3.3 Special Fire Fighting Procedures. . . . . None.
3.4 Flammability. . . . . . . . . . . . . . . . . . . . . . . . . . Non combustible.
4 SAFE HANDLING INFORMATION

4.1 Storage/Transport..................... No special storage and transport requirements. ' This product has no UN classification. This product is a S6 Poison. Observe all relevant regulations regarding sale, transport and storage of this class of product. Containers should be kept closed in order to minimise contamination. Keep from extreme heat and open flames

4.2 Packaging/Labelling

UN No . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Not applicable.
Pack Group. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Not applicable.
Class. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Not applicable.
Hazchem Code. . . . . . . . . . . . . . . . . . . . . . . . . . . Not applicable.
Subs Risk. . . . . . . . . . . . . . . : . . . . . . . . . . . . . . . . Not applicable.
EPG No . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Not applicable.
Shipping Name. . . . . . . . . . . . . . . . . . . . . . . . . . . . Organic agricultural amendment.
Hazard. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Not applicable.
4.3 Spills and Disposal

Spilled Material. . . . . . . . . . . . . . . . . . . . . . . . . . . . Land: ventilate area of spill and clean up. Water: flush with clean water.
Disposal. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Dispose of in accordance with local and national . regulations.

4.4 Fire/Explosion Hazard

Fire/Explosion. . . '. . . . . . . . . . . . . . . . . . . . . . . . . None.
Extinguishing Media. . . . . . . . . . . . . . . . . . . . . . . . Material is non-combustible, however as product has oil residue, use CO2 or polymer foam.
5
OTHER INFORMATION. . . . . . . . . . . . . . No data available.

DISCLAIMER
The data and recommendations presented herein are based upon research of others and are believed to be accurate. However, no warranty is expressed or implied regarding this data or the results to be obtained from use thereof. Garden Enterprises and Information Ltd, assumes no responsibility for the injury to customers or third party proximity caused by the material if reasonable safety procedures are not adhered to as stipulated in this data sheet. .

Reviewed 11th Septmeber 2017


MATERIAL SAFETY DATA SHEET
POTASSIUM NITRATE SDC615

STATEMENT OF HAZARDOUS NATURE: This material is classified as a Hazardous material according to the criteria of NZS 5433:1999 "Transport of Dangerous Goods on Land" This material is a scheduled poison according to the criteria of the Toxic Substances Regulations 1983.
IDENTIFICATION

Product Name: Potassium Nitrate
Other Name: Nitrate of Potash, salt peter, Stump Rotter
Manufacturer's Product Code: Not Applicable
U.N. Number: 1486
Dangerous Goods Class: 5.1
Packaging Group: III
Hazchem Code: 1[Z]
Toxic Substances Schedule: 3
Physical Description/Properties
Appearance: Transparent, colourless or white crystalline powder or crystals slightly hydroscopic.
Boiling Point/Melting Point: MP: 333oC BP: decomposes 750oC
Vapour Pressure: <1 mm Hg
Specific Gravity: 2.1062
Flash Point: >150oC (TCC)
Flammability Limits: Not available
Solubility in Water: 31.6 g/100ml (20oC)
Other Properties: Slightly soluble in glycerol, soluble in alcohol.

Ingredients
Chemical Entity CAS No Proportion
Potassium Nitrate 7757-79-1 97.5
Heavy Metals - less than 10ppm
Inerts - to 100%
HEALTH HAZARD INFORMATION
Health Effects
Acute
Swallowed: Low toxicity. May induce dizziness, abdominal cramps, vomiting and bloddy diarrhoea if large quantities ingested.
Eye: May cause mild irritation.
Skin: Mild irritation.
Inhaled: May cause irritation of the mouth and throat.
Chronic No data available.
First Aid
Swallowed: Rinse mouth with milk or water. Induce vomiting by either administering an emetic syrup or putting fingers down throat. Seek urgent medical assistance.
Eye: Flush affected eye(s) with copious amounts of cold or luke warm water for at least 15 minutes retracting eyelids frequently. Seek medical assistance.
Skin: Flood affected area with copious amounts of soap and water, remove contaminated clothing and launder before reuse. If rash or discolouration appears or persists seek medical assistance.
Inhaled: May cause irritation of the mouth and throat.
Advice to Doctor: Treat symptomatically. Refer to National Poisons and Hazardous Chemicals Information Centre.
PRECAUTIONS FOR USE
Exposure Standards: Not listed. NZ WES-TWA : Nuisance Dust 10mg/m3
Engineering Controls: Use in well ventilated area. Use protective breathing apparatus as required.
Personal Protection: Wear overalls, rubber gloves and goggles when handling. Wear respirator if local exhaust ventilation inadequate.
Flammability: Non flammable. Oxidising agent, will cause fires to burn with greater intensity and may cause explosions. Oxides of nitrogen may form.
SAFE HANDLING INFORMATION
Storage and Transport: Keep away from metals and combustibles and with any other class of hazardous goods. Store in cool, dark areas.
Spills and Disposal: Wear protective equipment. Sweep up but avoid generating dust. Prevent contamination of drains and waterways. Collect and seal in containers for disposal in accordance with local authority regulations
Fire/Explosion Hazard: Oxidising agent; when subjected to heat, nitrogen oxide fumes are given off. Will increase the intensity of any fire and the possibility of explosions.
OTHER INFORMATION
CONTACT POINT
Clark Products Ltd, 24-28 Niven Street Napier
Business Hours 8am to 5pm Monday to Friday
Phone : (06) 843 6049 Fax (06) 843 2758
24 HOUR EMERGENCY HELP
Phone : 0800CHEMCALL (0800 243 622)
National Poisons and Hazardous Chemicals Information Centre
Phone (03) 474 7000
This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all current legislation.

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MATERIAL SAFETY DATA SHEET
SODIUM CARBONATE SDC705
STATEMENT OF HAZARDOUS NATURE: This material is not classified as a Hazardous material according to the criteria of NZS 5433:1999 "Transport of Dangerous Goods on Land" This material is not a scheduled poison according to the criteria of the Toxic Substances Regulations 1983.
IDENTIFICATION
Product Name: Sodium Carbonate
Other Name: Soda Ash, Carbonic Acid (Disodium Salt), Dry Alkali.
Manufacturer's Product Code: Not Applicable.
U.N. Number: None Allocated
Dangerous Goods Class: None Allocated
Packaging Group: None Allocated
Hazchem Code: None Allocated
Toxic Substances Schedule: Not Listed
Physical Description/Properties
Appearance: White crystalline or granular solid.
Boiling Point/Melting Point: MP: 851oC
Vapour Pressure: Not available
Specific Gravity: 2.530
Flash Point: Not available
Flammability Limits: Not available
Solubility in Water: Soluble
Other Properties: Insoluble in alcohol
Ingredients
Chemical Entity CAS No Proportion
Sodium Carbonate 497-19-8 100%
HEALTH HAZARD INFORMATION
Health Effects
Acute
Swallowed: Ingestion of large amounts could cause nausea, vomiting and diarrhoea.
Eye: Strong irritant to soft tissue and eyes.
Skin: Irritant to skin, particularly if skin is wet or moist due to sweating. Solutions are severely irritant due to alkaline nature.
Inhaled: Will result in respiratory and nasal irritation.
Chronic No data available.
First Aid
Swallowed: Do NOT induce vomiting. Rinse mouth with milk or water. Give large amounts of water or milk to drink to achieve dilution. If vomiting occurs give further milk or water. Seek urgent medical assistance.
Eye: Flush affected eye(s) with copious amounts of cold or luke warm water for at least 15 minutes retracting eyelids frequently. Seek medical assistance.
Skin: Flood affected area with copious amounts of soap and water, remove contaminated clothing and launder before reuse. If rash or discolouration appears or persists seek medical assistance.
Inhaled: Remove to fresh air, loosen restrictive clothing. Blow nose thoroughly and swab nasal passages with damp cotton wool. Allow to rest and keep warm. If recovery is not rapid and complete seek medical assistance.
Advice to Doctor: Treat symptomatically. Refer to National Poisons and Hazardous Chemicals Information Centre.
PRECAUTIONS FOR USE
Exposure Standards: Not listed. NZ WES-TWA : Nuisance Dust 10mg/m3
Engineering Controls: Use in well ventilated area. Use protective breathing apparatus as required.
Personal Protection: Wear overalls, rubber gloves and goggles when handling. Wear repirator if local exhaust ventilation inadequate.
Flammability: Non Flammable.
SAFE HANDLING INFORMATION
Storage and Transport: Keep dry and away from acids.
Spills and Disposal: Wear protective equipment. Sweep up but avoid generating dust. Prevent contamination of drains and waterways. Collect and seal in containers for disposal in accordance with local authority regulations
Fire/Explosion Hazard: No hazard in normal use and storage. Will react violently with acids releasing heat and carbon dioxide.
OTHER INFORMATION
CONTACT POINT
Clark Products Ltd, 24-28 Niven Street Napier
Business Hours 8am to 5pm Monday to Friday
Phone : (06) 843 6049 Fax (06) 843 2758
24 HOUR EMERGENCY HELP
Phone : 0800CHEMCALL (0800 243 622)
National Poisons and Hazardous Chemicals Information Centre
Phone (03) 474 7000
This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all current legislation.

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MATERIAL SAFETY DATA SHEET
AMMONIUM SULPHATE SDC065

STATEMENT OF HAZARDOUS NATURE: This material is not classified as a Hazardous material according to the criteria of NZS 5433:1999 "Transport of Dangerous Goods on Land". This material is not a scheduled poison according to the criteria of the Toxic Substances Regulations 1983.
IDENTIFICATION
Product Name: Ammonium Sulphate
Other Name: Not Applicable
Manufacturer's Product Code: Not Applicable
U.N. Number: None Allocated
Dangerous Goods Class: None Allocated
Packaging Group: None Allocated
Hazchem Code: None Allocated
Toxic Substances Schedule: Not Listed
Physical Description/Properties
Appearance: Brownish grey to white crystals
Boiling Point/Melting Point: Decomposes above 235oC
Vapour Pressure: Not available
Specific Gravity: 1.77
Flash Point: Not Available
Flammability Limits: Not Available
Solubility in Water: 76g/100ml
Other Properties:
Ingredients
Chemical Entity CAS No Proportion
Ammonium Sulphate 7783-20-2 99.5%
Inerts - to 100%
HEALTH HAZARD INFORMATION
Health Effects
Acute
Swallowed: Low to medium toxicity may cause sore throat, abdominal pain, nausea and vomiting.
Eye: Dust will cause moderate irritation redness and watering.
Skin: Moderate irritant may cause redness or itching.
Inhaled: Moderate irritant may cause sore throat and/or coughing.
Chronic No data available
First Aid
Swallowed: Rinse mouth with milk or water. Induce vomiting by either administering an emetic syrup or putting fingers down throat. Seek urgent medical assistance.
Eye: Flush affected eye(s) with copious amounts of cold or luke warm water for at least 15 minutes retracting eyelids frequently. Seek medical assistance.
Skin: Flood affected area with copious amounts of soap and water, remove contaminated clothing and launder before reuse. If rash or discolouration appears or persists seek medical assistance.
Inhaled: Remove victim to fresh air loosen restrictive clothing and allow to rest. Keep warm. If recovery is not rapid and complete seek medical assistance.
Advice to Doctor: Treat symptomatically. Refer to National Poisons and Hazardous Chemicals Information Centre.
PRECAUTIONS FOR USE
Exposure Standards: Not listed. NZ WES-TWA : Nuisance Dust 10mg/m3
Engineering Controls: Use in well ventilated area. Use protective breathing apparatus as required.
Personal Protection: Wear overalls, rubber gloves and goggles when handling. Wear repirator if local exhaust ventilation inadequate.
Flammability: Non Flammable.
SAFE HANDLING INFORMATION
Storage and Transport: Keep cool and dry. Store away from bases and heat. Corrosive to metals.
Spills and Disposal: Wear protective equipment. Sweep up but avoid generating dust. Prevent contamination of drains and waterways. Collect and seal in containers for disposal in accordance with local authority regulations
Fire/Explosion Hazard: Non flammable. Stable at ambient temperatures. Does not support combustion. Use firefighting media suitable for surrounding fire. Decomposes to release toxic sulphur dioxide fumes.
OTHER INFORMATION
CONTACT POINT
Clark Products Ltd, 24-28 Niven Street Napier
Business Hours 8am to 5pm Monday to Friday
Phone : (06) 843 6049 Fax (06) 843 2758
24 HOUR EMERGENCY HELP
Phone : 0800CHEMCALL (0800 243 622)
National Poisons and Hazardous Chemicals Information Centre
Phone (03) 474 7000
This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all current legislation.

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MATERIAL SAFETY DATA SHEET
Tergitol NP9

STATEMENT OF HAZARDOUS NATURE: This material is classified as a Hazardous material according to the criteria of NZS 5433:1999 "Transport of Dangerous Goods on Land" This material is not a scheduled poison according to the criteria of the Toxic Substances Regulations 1983.
IDENTIFICATION
Product Name: Tergitol NP9
Other Name: Nonylphenol Ethoxylate
Manufacturer's Product Code: Not Applicable
U.N. Number: 3082
Dangerous Goods Class: 9 (Environmentally Hazardous Substance)
Packaging Group: III
Hazchem Code: 2X
Toxic Substances Schedule: Not Listed
Physical Description/Properties
Appearance: Clear to hazy viscous liquid.
Boiling Point/Melting Point: BP:> 250oC, MP 3.8oC
Vapour Pressure: <0.01mm Hg (20oC)
Specific Gravity: 1.057 (20/20oC)
Flash Point: 247oC (Pensky-Martens c.c.)
Flammability Limits: Not available
Solubility in Water: Soluble
Other Properties: Soluble in most organic solvents
Ingredients
Chemical Entity CAS No Proportion
Nonyl phenol
Ethoxylated with 9 moles of ethylene oxide 9016-45-9 100%
HEALTH HAZARD INFORMATION
Health Effects
Acute
Swallowed: May cause abdominal discomfort, nausea, vomiting and diarrhoea. Aspiration into lungs may cause injury.
Eye: Causes severe irritation with possible chemical burns of the eye.
Skin: Will have a degreasing effect on the skin. Brief contact is not irritating. Prolonged contact my cause redness.
Inhaled: Not normally an inhalation hazard due to low vapour pressure at ambient temperature.
Chronic Repeated or prolonged contact may lead to dermatitus
First Aid
Swallowed: Do NOT induce vomiting. Rinse mouth with milk or water. Give large amounts of water or milk to drink to achieve dilution. If vomiting occurs give further milk or water. Seek urgent medical assistance.
Eye: Flush affected eye(s) with copious amounts of cold or luke warm water for at least 15 minutes retracting eyelids frequently. Seek medical assistance.
Skin: Flood affected area with copious amounts of soap and water, remove contaminated clothing and launder before reuse. If rash or discolouration appears or persists seek medical assistance.
Inhaled: Remove victim to fresh air loosen restrictive clothing and allow to rest. Keep warm. If recovery is not rapid and complete seek medical assistance.
Advice to Doctor: Treat symptomatically. Refer to National Poisons and Hazardous Chemicals Information Centre.
PRECAUTIONS FOR USE
Exposure Standards: Not listed.
Engineering Controls: Natural ventilation should be adequate under normal use conditions. Avoid generating and inhaling dust.
Personal Protection: Wear overalls, rubber gloves and goggles when handling.
Flammability: Combustible liquid.
SAFE HANDLING INFORMATION
Storage and Transport: Normally unreactive. Do not store with oxidising agents. Keep containers closed when not in use.
Spills and Disposal: Slippery when spilt. Avoid accidents and clean up immediately. Small spills of liquid should be absorbed with suitable inert dry matter such as sand or diatomaceous earth. For large spills, prevent liquid from spreading by use of sand, etc. Transfer recovered liquid to salvage tank or drum. Treat residues as for small spillage. Dispose of any contaminated material in accordance with local authority regulations.
Fire/Explosion Hazard: Burning can produce carbon monoxide or carbon dioxide.
OTHER INFORMATION
CONTACT POINT
Clark Products Ltd, 24-28 Niven Street Napier
Business Hours 8am to 5pm Monday to Friday
Phone : (06) 843 6049 Fax (06) 843 2758
24 HOUR EMERGENCY HELP
Phone : 0800CHEMCALL (0800 243 622)
National Poisons and Hazardous Chemicals Information Centre
Phone (03) 474 7000
This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all current legislation.

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